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Crystal structure of bis(1-thia-4,7-diazacyclononane)copper(II) perchlorate

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Summary

The cation, bis(1-thia-4,7-diazacyclononane)copper(II), in the perchlorate salt, has the metal atom on a crystallographic twofold axis, and is dissimilar to the nitrate, where the metal is at a centre of symmetry.

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Authors and Affiliations

  1. Department of Chemistry, University of Queensland, Q. 4067, St. Lucia, Brisbane, Australia

    Lawrence R. Gahan & Colin H. L. Kennard

  2. Department of Chemistry, Queensland Institute of Technology, Q. 4000, Brisbane, Australia

    Graham Smith

  3. Department of Chemistry, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong

    Thomas C. W. Mak

Authors
  1. Lawrence R. Gahan
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  2. Colin H. L. Kennard
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  3. Graham Smith
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  4. Thomas C. W. Mak
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Additional information

Atomic co-ordinates, thermal parameters, and lists of structure factors have been deposited as supplementary data with the Editor, from whom copies are available on request. Atomic coordinates have also been deposited with the Cambridge Crystallographic Data Centre.

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Gahan, L.R., Kennard, C.H.L., Smith, G. et al. Crystal structure of bis(1-thia-4,7-diazacyclononane)copper(II) perchlorate. Transition Met Chem 11, 465–466 (1986). https://doi.org/10.1007/BF01386877

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  • DOI: https://doi.org/10.1007/BF01386877

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