Summary
A new series of cyano-substituted nitrosylchromium(I) complexes having octahedral stereochemistry around the metal ion, and of general formula, [CrNO(CN)2(L)2(H2O)] (L =o-,m- andp-phenetidines oro-,m-, andp-anisidines) have been isolated in the solid state by interaction of potassium pentacy-anonitrosylchromate(I) monohydrate with the appropriately substituted aniline. The complexes, which have been characterised by elemental analysis, conductance, molecular weight determination, magnetic measurements, e.s.r. and i.r. spectral studies, contain chromium(I) in a low-spin d5-configuration.
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Maurya, R.C., Gupta, D.C., Shukla, R. et al. Synthesis and characterisation of some new cyanonitrosyl chromium(l) complexes with phenetidines and anisidines. Transition Met Chem 11, 463–464 (1986). https://doi.org/10.1007/BF01386876
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DOI: https://doi.org/10.1007/BF01386876