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The role of small silver clusters in photography

Abstract

Size-selected silver cluster ions have been produced in a mass spectrometer arrangement and have been deposited onto binder-free AgBr microcrystals. Clusters containing less than four silver atoms did not catalyze development (reduction) of the microcrystals. However, application of clusters containing four or more silver atoms rendered the crystals immediately developable in a conventional photographic developer. This for the first time proves directly, that a so-called latent image speck under these conditions of development requires a minimum number of four silver atoms.

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References

  1. 1.

    Frieser, H., Haase, G., Klein, E. (ed.): Die Grundlagen der photographischen Prozesse mit Silberhalogeniden. Frankfurt/M.: Akadem. Verlagsges. 1968

    Google Scholar 

  2. 2.

    James, T.H. (ed.): The theory of the photographic process. 4th. Edn. New York, London: Macmillan Publ. Co. 1977

    Google Scholar 

  3. 3.

    Granzer, F., Moisar, E.: Physik in unserer Zeit12, 22, 36 (1981)

    Google Scholar 

  4. 4.

    Moisar, E.: Chemie in unserer Zeit17, 85 (1983)

    Google Scholar 

  5. 5.

    James, T.H., Vanselow, W., Quirk, R.F.: PSA J.14, 349 (1948)

    Google Scholar 

  6. 6.

    Hamm, F.A., Comer, J.J.: J. Appl. Phys.24, 1495 (1953)

    Google Scholar 

  7. 7.

    Gurney, R.W., Mott, N.F.: Proc. R. Soc. A164, 151 (1938)

    Google Scholar 

  8. 8.

    Mitchell, J.W.: J. Phys. Chem.66, 2359 (1962)

    Google Scholar 

  9. 9.

    Mitchell, J.W.: Photogr. Sci. Eng.22, 1, 249 (1978),23, 1 (1979)

    Google Scholar 

  10. 10.

    Malinowski, J.: Photogr. Sci. Eng.14, 112 (1970)

    Google Scholar 

  11. 11.

    Moisar, E., Granzer, F., Dautrich, D., Palm, E.: J. Photogr. Sci.25, 12 (1977),28, 71 (1980)

    Google Scholar 

  12. 12.

    Moisar, E.: Photogr. Sci. Eng.26, 124 (1982)

    Google Scholar 

  13. 13.

    Hillson, P.J.: J. Photogr. Sci.22, 31 (1974)

    Google Scholar 

  14. 14.

    Konstantinov, I., Malinowski, J.: J. Photogr. Sci.23, 1, 145 (1975)

    Google Scholar 

  15. 15.

    Fayet, P., Wöste, L.: Z. Phys. D — Atoms, Molecules and Clusters3, 177 (1986)

    Google Scholar 

  16. 16.

    Galashin, E.A., Senchenkov, E.P., Chibisov, K.V.: Dokl. Akad. Nauk SSSR181, 124 (1969)

    Google Scholar 

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Fayet, P., Granzer, F., Hegenbart, G. et al. The role of small silver clusters in photography. Z Phys D - Atoms, Molecules and Clusters 3, 299–302 (1986). https://doi.org/10.1007/BF01384819

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PACS

  • 82.50. −m
  • 07.68. +m
  • 36.40. +d