Abstract
The possibility of direct one-electron electrochemical introduction of nitrogen monoxide as a nitroso group into a number of organic compounds was demonstrated. Depending on the conditions, this process may occur both by electrochemical activation of the substrate and by activation of NO, which opens up new approaches to the production of organic nitroso derivatives.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. D. Pokhodenko, V. G. Koshechko, V. E. Titov, and D. V. Sednev, Teor. Éksp.Khim.,28, No. 2. 98–114 (1992).
M. M. Baizer. Tetrahedron,40, No. 6. 935–969 (1984).
J. Chaussard, J. C Folest,. J. Y. Nedelec, et al., Synthesis, No. 5. 369–38l (1990).
M. Baizer and H. Lund (eds.), Organic Electrochemistry [Russian translation], Vol. l. Khimiya, Moscow (1988).
G. M. Brauer (ed.). Manual of Inorganic Synthesis [Russian translation], Vol. 2. Mir. Moscow (1985).
A. Gordon and R. Ford. The Chemist's Companion [Russian translation]. Mir. Moscow (1976).
O. Cauquin, V. Delhomme, and D. Serve, Electrochim. Acta,20, No. 12, 1019–1026 (1975).
V. G. Koschechko and A. N. Inozemtsev. Zb. Obsch. Khim.53. No. 9. 2119–2122 (1982).
R. G. Keller, Sigma Library of FT-IR Spectra, St. Louis. Sigma Chemical. Vols. 1–2 (1986), p. 1547.
Additional information
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauki Prospekt, Kiev, 252039, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 32, No. 1, pp. 28–31, January–February, 1996. Original article submitted May 25, 1995.
Rights and permissions
About this article
Cite this article
Koshechko, V.G., Shpil'nyi, S.A. & Pokhodenko, V.D. Electrochemically activated introduction of nitrogen monoxide into organic substrates. Theor Exp Chem 32, 27–29 (1996). https://doi.org/10.1007/BF01372536
Issue Date:
DOI: https://doi.org/10.1007/BF01372536