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Influence of water molecules on dimerization of silicic acid

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Theoretical and Experimental Chemistry Aims and scope

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Abstract

By means of the quantum-chemical MO LCAO SCF method in the valence approximation of MNDO, it has been shown that effective interaction of two molecules of Si(OH)4 is possible with the participation of a water molecule that plays the role of a bridge in forming a six-center complex.

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Literature cited

  1. R. K. Iler, The Chemistry of Silica, Wiley, New York (1979).

    Google Scholar 

  2. A. A. Chuiko, I. P. Beletskii, and Yu. A. Gorlov, Dokl. Akad. Nauk SSSR, 303, No, 5 (1988).

  3. I. P. Beletskii, V. E. Klimenko, and A. A. Chuiko, Dokl. Ajad. Nauk SSSR,315, No. 3, 633 (1990).

    Google Scholar 

  4. I. P. Beletskii and V. E. Klimenko, Teor. Éksp. Khim.,27, No. 2 (1991).

  5. K. Ya. Burshtein and A. N. Isaev, Zh. Strukt. Khim.,27, No. 3, 3–7 (1986).

    Google Scholar 

  6. B. Kh. Khalbaev and I. A. Misurkin, Teor. Éksp. Khim.,24, No. 5, 532–545 (1980).

    Google Scholar 

  7. Yu. I. Gorlov, V. A. Zaets, and A. A. Chuiko, Teor. Éksp. Khim.,24, No. 5, 532–545 (1988).

    Google Scholar 

  8. T. Seidl and H. F. Scheefer, J. Am. Chem. Soc.,111, No. 5, 1569–1574 (1989).

    Google Scholar 

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Additional information

Institute of Surface Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 27, No. 4, pp. 485–487, July–August, 1991. Original article submitted February 14, 1991.

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Beletskii, I.P., Klimenko, V.E. Influence of water molecules on dimerization of silicic acid. Theor Exp Chem 27, 424–425 (1991). https://doi.org/10.1007/BF01372522

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  • DOI: https://doi.org/10.1007/BF01372522

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