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Crystal structure of copper bis(tenuazonate) monohydrate

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Abstract

The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic,P21, witha = 13.77(1),b = 15.51(1),c = 11.14(1) Å, β = 109.5(2) °, and two formula units, C20H26CuN2O6·H2O, per asymmetric unit. The structure was refined by full-matrix least squares toR = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.

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Author notes

  1. A. Dippenaar

    Present address: National Institute for Metallurgy, Randburg

  2. J. C. A. Boeyens

    Present address: National Chemical Research Laboratory, P.O. Box 395, 0001, Pretoria, South Africa

Authors and Affiliations

  1. Department of Chemistry, Rand Afrikaans University, Johannesburg

    A. Dippenaar, C. W. Holzapfel & J. C. A. Boeyens

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  1. A. Dippenaar
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  2. C. W. Holzapfel
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  3. J. C. A. Boeyens
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NIM Applied Structural Chemistry Research Group

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Dippenaar, A., Holzapfel, C.W. & Boeyens, J.C.A. Crystal structure of copper bis(tenuazonate) monohydrate. Journal of Crystal and Molecular Structure 7, 189–197 (1977). https://doi.org/10.1007/BF01371471

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  • DOI: https://doi.org/10.1007/BF01371471

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