Abstract
An empirical equation ΔH s, m=0.84n′ gives the enthalpy of solution of 30 branched, linear and cyclic alkanes in glacial acetic acid. The parametern′ is an “effective carbon number” which expresses the number of carbon atoms in the longest chain plus one half of the pendant methyl groups.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. W. Rogers, B. Munoz-Hresko, R. R. Mandra,Mikrochim. Acta [Wien] 1984,II, 417.
D. W. Rogers, L. S. Choi, J. Beauregaard,Mikrochim. Acta [Wien] 1980,I, 138.
D. W. Rogers, J.-H. Kim,Mikrochim. Acta [Wien] 1985,III, 297.
R. B. Turner, A. D. Jarrett, P. Goebel, B. J. Mallon,J. Amer. Chem. Soc. 1973,95, 790, and previous papers.
D. W. Rogers, P. M. Papadimetriou, N. A. Siddiqui,Mikrochim. Acta [Wien] 1973, 389; D. W. Rogers, O. A. Dagdagan, N. L. Allinger,J. Amer. Chem. Soc. 1979,101, 671.
W. Hemminger, G. Hohne,Calorimetry, Fundamentals and Practice, Verlag Chemie, Weinheim, 1984, Chapt. 6.2.
D. W. Rogers, B. J. Siedman,Talanta (in press).
D. W. Rogers, S. C. Patel,Mikrochim. Acta [Wien] 1982, 383.
M. J. Kamlet, R. Doherty, R. W. Taft, M. H. Abraham,J. Amer. Chem. Soc. 1983,105, 6741; M. J. Kamlet, J. L. M. Aboud, R. W. Taft,Progress in Physical Organic Chemistry 1981,13, 485.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rogers, D.W., Kim, JH. Microcalorimetric determination of enthalpies of solution of methyl alkanes in glacial acetic acid. Mikrochim Acta 90, 259–266 (1986). https://doi.org/10.1007/BF01364306
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01364306