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Intermediate valence theory of CePd3 and UNi5−x Cu x

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Zeitschrift für Physik B Condensed Matter

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Abstract

The variation with temperature of the lattice constant and paramagnetic susceptibility of CePd3 are reproduced theoretically on the basis of a model which takes into account the interaction of conduction- andf-electrons and the finite width of thef-band. The same model, with added exchange, yields quantitative agreement with susceptibility measurements on UNi5−x Cu x compounds (x=5 and 4.6). The theory also supplies a microscopic basis to the phenomenological model of Sales and Wohlleben.

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References

  1. Harris, I.R., Norman, M., Gardener, W.E.: J. Less Common Metals29, 299 (1972)

    Google Scholar 

  2. Gardener, W.E., Penfold, J., Smith, T.F., Harris, I.R.: J. Phys. F2, 133 (1972)

    Google Scholar 

  3. Holland-Moritz, E., Loewenhaupt, M., Schmatz, W., Wohlleben, D.: Phys. Rev. Lett.38, 983 (1977)

    Google Scholar 

  4. Daal, H.J. van, Buschow, K.H.J., Aken, P.B. van, Maaren, M.H. van: Phys. Rev. Lett.34, 1457 (1975)

    Google Scholar 

  5. Grohs, H., Hochst, H., Steiner, P., Hufner, S., Buschow, K.H.J.: Solid State Commun.33, 573 (1980)

    Google Scholar 

  6. Murasik, A. Ligenza, S., Zygmunt, A.: Phys. Status Solidi (a)23, K163 (1974)

    Google Scholar 

  7. Falicov, L.M., Kimball, J.C.: Phys. Rev. Lett.22, 997 (1969)

    Google Scholar 

  8. Ramirez, R., Falicov, L.M., Kimball, J.C.: Phys. Rev. B2, 3383 (1970)

    Google Scholar 

  9. Pickett, W.E., Freeman, A.J., Koelling, D.D.: Phys. Rev. B23, 1266 (1981)

    Google Scholar 

  10. Hubbard, J.: Proc. R. Soc. A276 238 (1963)

    Google Scholar 

  11. Haley, S.B., Erdös, P.: Phys. Rev. B5, 1106 (1972)

    Google Scholar 

  12. Robinson, J.M.: American Institute of Physics Conference Proceedings (USA), no. 34, 189 (1976); Robinson, J.M., Erdös, P.: Phys. Rev. B8, 4333 (1973)

    Google Scholar 

  13. The contribution of thef n−1 configuration tom (induced moment) is calculated in Rauchwarger, K., Jafarey, S., Wang, Y.-L.: Phys. Rev. B2, 3383 (1970), and in ref. 18. In the applications discussed here, this contribution is negligible

    Google Scholar 

  14. Lea, K.R., Leask, M.J., Wolf, W.P.: J. Phys. Chem. solids23, 1381 (1962)

    Google Scholar 

  15. Chan, S.K., Lam, D.J.: In: The actinides: electronic structure and related properties. Freeman, A.J., Darby, B.J. (Jr.) (eds.) Academic Press, N.Y. 1974

    Google Scholar 

  16. In those actinide compounds where the energy separation between the narrowf-level and the bottom of the conduction band is of the same order of magnitude asG, the interaction whose strength isG has an important role in causing first-order magnetic phase transitions; see e.g. Ref. 12 —

    Google Scholar 

  17. Sales, B.C., Wohlleben, D.K.: Phys. Rev. Lett.35, 1240 (1975)

    Google Scholar 

  18. Varma, C.M.: Rev. Mod. Phys.48, 219 (1976)

    Google Scholar 

  19. Robinson, J.M.: Phys. Rep.51, 1 (1979)

    Google Scholar 

  20. Razafimandimby, H.A.: Physica102B, 91 (1980)

    Google Scholar 

  21. Razafimandimby, H.A.: Thesis 1981, Faculté des Sciences, Université de Lausanne (unpublished). Copies may be obtained from the author

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Razafimandimby, H.A., Erdös, P. Intermediate valence theory of CePd3 and UNi5−x Cu x . Z. Physik B - Condensed Matter 46, 193–197 (1982). https://doi.org/10.1007/BF01360293

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  • DOI: https://doi.org/10.1007/BF01360293

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