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Inelastic and quasi-elastic light scattering in (NaCN)1−x(KCN)x quadrupolar glasses

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Zeitschrift für Physik B Condensed Matter

Abstract

The elastic constantsc 11 andc 44, and the attenuation of longitudinal phonons along (100)-direction in (NaCN)1−x(KCN)x mixed crystals have been determined by brillouin spectroscopy in the temperature range fromT=10K−300K. Minima inc 44 (T) which determine the freezing tempratureT F in these orientational glasses appear at lower temperatures compared to neutron scattering results. The coupling of molecular reorientations to longitudinal phonons in NaCN-rich smaples shows up in dispersion effects inc 11 (T) and the appearence of a dynamical central peak nearT F .

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U.A. 1119 is associated to the Centre National de la Recherche Scientifique

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Berret, J.F., Feile, R. Inelastic and quasi-elastic light scattering in (NaCN)1−x(KCN)x quadrupolar glasses. Z. Physik B - Condensed Matter 80, 203–206 (1990). https://doi.org/10.1007/BF01357503

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  • DOI: https://doi.org/10.1007/BF01357503

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