Abstract
A bipolaronic model of high-T c superconductivity, that is based upon the idea that a doped oxygenhole reduces the separation between the\(d_{x^2 - y^2 }\) and\(d_{3z^2 - r^2 }\) levels of the neighbouring Cu-ion and hence causes a Jahn-Teller mixing between the two levels, is suggested. Within the BCS scheme, the bipolaron Hamiltonian is investigated for the superconducting order parameter Δ and the critical temperatureT c as a function of hole-doping. Under suitable approximation for the bipolaronic kinetic energy, the hole-doping dependence ofT c shows a universal behaviour. For temperatures close toT c and forT c ≫1, Δ obeys the BCS type of relation with pre-factor of (1−T/T c )2 related to the range of superconducting-phase against the doping axis.
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Thakur, J.S., Rai, R. Dependence ofT c on doping in oxygen-hole induced Jahn-Teller mediated superconductors. Z. Physik B - Condensed Matter 91, 285–290 (1993). https://doi.org/10.1007/BF01344057
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DOI: https://doi.org/10.1007/BF01344057