Abstract
Thin films of binary systems KCl/TlCl and RbCl/TlCl are condensated onto a substrate at low temperature (quenching condensation). Debye-Scherrer-Photographs are taken immediately after condensation and during annealing. After condensation at 20 ‡K the films have a high degree of disorder, under certain conditions the films are forced even in an amorphous state. CsCl-type structure is found at high concentrations of TlCl, the films exhibit NaCl-type structure with increasing concentrations of KCl and RbCl. Diagrams of the frozen-in states of the condensated films are compared to the usual equilibrium diagrams of the binary systems.
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Meinem hochverehrten Lehrer, Herrn Professor Dr. R.Hilsch, und Herrn Privatdozenten Dr. W.Martienssen bin ich zu großem Dank verpflichtet für die Anregung zu dieser Arbeit und ihre stete Förderung. Herrn Dr.Queisser, Herrn Dr.Rühl und Herrn Dr.Sander danke ich für viele wertvolle Hinweise und Diskussionen. Für die Durchführung der Arbeit waren Mittel der Deutschen Forschungsgemeinschaft wesentlich.
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Mittendorf, H. Zur Struktur dünner, bei tiefer Temperatur kondensierter Salzschichten. Z. Physik 163, 321–338 (1961). https://doi.org/10.1007/BF01342491
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DOI: https://doi.org/10.1007/BF01342491