Skip to main content
Log in

Thermodynamic metric and stochastic measures

  • Published:
Zeitschrift für Physik B Condensed Matter

Abstract

A modification of the thermodynamic Weinhold metric is introduced by the statistical scheme of bit-number cumulants discussed in earlier papers. It is a metric in the space of intensive thermal variables and becomes identical with the Weinhold metric if transformed into the space of extensive variables. The quadratic forms of the metric tensor are different for finite distances. The here presented metric is signified by quantities defined in general statistics, distinguished by important invariance properties and moreover it brings simplifications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Weinhold, F.: J. Chem. Phys.63, 2479 (1975);63, 2482 (1975);63, 2488 (1975);63, 2496 (1975);65, 559 (1976)

    Google Scholar 

  2. Salamon, P., Andresen, B., Gait, P.D., Berry, R.S.: J. Chem. Phys.73, 1001 (1980)

    Google Scholar 

  3. Salamon, P., Berry, R.S.: Phys. Rev. Lett.51, 1127 (1983)

    Google Scholar 

  4. Rupeiner, G.: Phys. Rev. A20, 1608 (1979);24, 488 (1981);27, 1116 (1983); Phys. Rev. Lett.50, 287 (1983)

    Google Scholar 

  5. Salamon, P., Nulton, J., Ihrig, E.: J. Chem. Phys.80, 436 (1984)

    Google Scholar 

  6. Nulton, J., Salamon, P., Andresen, B., Qi Anmin: Quasistatic processes as step equilibrations. J. Chem. Phys. (submitted for publication)

  7. Nulton, J., Salamon, P.: The geometry of the ideal gas. Phys. Rev. A (to appear)

  8. Feldmann, T., Andresen, B., Anmin Qi, Salamon, P.: Thermodynamic lengths and intrinsic time scales in molecular relaxation. (draft) San Diego State University.

  9. Salamon, P., Nulton, J.D., Berry, R.S.: Length in statistical thermodynamics. J. Chem. Phys. (to appear)

  10. Flick, J.D., Salamon, P., Andresen, B.: Metric bounds on losses in adaptive coding. I.E.E.E. Transact. Inf. Theor. (submitted for publication)

  11. Schlögl, F.: Z. Phys. B — Condensed Matter20, 177 (1975);22, 301 (1975);52, 51 (1983); Phys. Rep.62, 267 (1980)

    Google Scholar 

  12. Jaynes E.T.: Phys. Rev.106, 620 (1957)

    Google Scholar 

  13. Kullback, S.: Ann. Math. Stat.22, 79 (1951); Information theory and statistics. New York: Wiley 1951

    Google Scholar 

  14. Schlögl, F.: Z. Phys.191, 81 (1966);198, 560 (1967)

    Google Scholar 

  15. Salamon, P., Nulton, J., Feldmann, T., Andresen, B.: Relaxation times and metric bounds on dissipation (draft). San Diego State University

  16. Hatsopoulos, G.N., Keeman, J.H.: Principles of general thermodynamics. New York: J. Wiley 1965

    Google Scholar 

  17. Schlögl, F.: Z. Phys.191, 81 (1966);198, 559 (1967);249, 1 (1971)

    Google Scholar 

  18. Schlögl, F.: Z. Phys.244, 199 (1971);248, 446 (1971);249, 1 (1971); Phys. Lett.26A, 193 (1971); Progr. Theor. Phys. Suppl.64, 100 (1978); Z. Phys. B — Condensed Matter33, 199 (1979)

    Google Scholar 

  19. Ruppeiner, G.: Phys. Rev. A27, 1116 (1983)

    Google Scholar 

  20. Glansdorff, P., Prigogine, I.: Physica46, 344 (1970)

    Google Scholar 

  21. Schlögl, F.: Z. Phys.243, 303 (1971); Thermodynamics and regulation of biological processes. Lamprecht, L., Zotin, A.I., (eds.). Berlin, New York: de Gruyter, 1985

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schlögl, F. Thermodynamic metric and stochastic measures. Z. Physik B - Condensed Matter 59, 449–454 (1985). https://doi.org/10.1007/BF01328857

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01328857

Keywords

Navigation