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The crystallization of Fe1−x P x , 0.09≦x≦0.26

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Zeitschrift für Physik B Condensed Matter

Abstract

The crystallization behaviour of about 60 samples of electrodeposited Fe1−x P x , 0.09<x<0.26, was investigated with DSC and X-ray diffraction. Several subsequenting transformations during heating at 10 K/min were identified. The corresponding transformation temperatures, reaction heats and reaction rates were measured. If the as-deposited samples contain metal-rich crystallites (microcrystalline and partly amorphous material) crystallization starts with primary precipitation of α-iron followed by polymorphous crystallization of Fe3P. In amorphous samples these two processes become less important compared with the eutectoid reaction the higher the phosphorus content. In a small concentration range around 19 at% P this transformation is the only one. Above this range the primary crystallization of Fe3P becomes more and more dominant.

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References

  1. Hansen, M., Anderko, D.: Constitution of binary alloys. 2nd Edn., p. 362. New York, Toronto, London: Mc-Graw-Hill 1958

    Google Scholar 

  2. Fukamichi, K., Kikuchi, M., Arakawa, S., Masumoto, T.: Solid State Commun.23, 955 (1977)

    Google Scholar 

  3. Fukamichi, K., Masumotu, T., Kikuchi, M.: IEEE Trans. Magn.15, 294 (1979)

    Google Scholar 

  4. Fukamichi, K., Hiroyoshi, H., Kikuchi, M., Masumoto, T.: J. Magn. Magn. Mater.10, 294 (1979)

    Google Scholar 

  5. Takahashi, M., Koshimura, M.: Jpn. J. Appl. Phys.16, 2269 (1977)

    Google Scholar 

  6. Musser, D., Chein, C.L.: J. Appl. Phys.50, 7659 (1979)

    Google Scholar 

  7. Tanaka, K., Soga, N., Kirao, K.: J. Appl. Phys.60, 728 (1986)

    Google Scholar 

  8. Miyazaki, T., Yang Xingbo, Takahashi, M.: J. Magn. Magn. Mater.60, 204 (1986)

    Google Scholar 

  9. Kim, Ch., Kim, T., Takahashi, M.: Proceedings of the 4th International Conference on Rapidly Quenched Metals, Sendai 1981, p. 723

  10. Hiltunen, E.J., Kesti, M., Ulvinen, A., Takács, L.: J. Mat. Sci. Lett.7, 441 (1988)

    Google Scholar 

  11. Hiltunen, E.J., Lehto, J.A.: Phys. Scr.34, 239 (1986)

    Google Scholar 

  12. Logan, J.: Phys. Status Solidi. (a)32, 361 (1975)

    Google Scholar 

  13. Logan, J., Yung, M.: J. Non-Cryst. Solids21, 151 (1976)

    Google Scholar 

  14. Logan, J., Sun, E.: J. Non-Cryst. Solids20, 285 (1976)

    Google Scholar 

  15. Dietz, G., Börngen, L.: J. Non-Cryst. Solids58, 275 (1983)

    Google Scholar 

  16. Hüller, K., Dietz, G., Hausmann, R., Kölpin, K.: J. Magn. Magn. Mater.53, 103 (1985)

    Google Scholar 

  17. Hüller, K., Dietz, G.: J. Magn. Magn. Mater.50, 250 (1985)

    Google Scholar 

  18. Dietz, G., Richter, K., Stein, F., Schäfer, H.C.: Z. Phys. B-Condensed Matter81, 223 (1990)

    Google Scholar 

  19. Hiltunen, E.J., Takács, L.: J. Mat. Sci.18, 1515 (1983)

    Google Scholar 

  20. Elsukov, L.P., Vorobev, Yu.N., Trubachev, A.V., Barinov, V.A.: Phys. Status Solidi (a)117, 291 (1990)

    Google Scholar 

  21. McCally, R.L., Moorjani, K.: J. Appl. Phys.67, 5784 (1990)

    Google Scholar 

  22. McNaughton, J.L., Mortimer, C.T.: IRS physical chemistry. Ser. 2, Vol. 10. London: Butterworth 1974

    Google Scholar 

  23. Watson, E.S., O'Neil, M.J., Justin, J., Brenner, N.: Anal. Chem.36, 1233 (1964)

    Google Scholar 

  24. Guttmann, C.M., Flynn, J.H.: Anal. Chem.45, 408 (1973)

    Google Scholar 

  25. Johnson, W.A., Mehl, K.F.: Trans. Am. Inst. Min. Metall. Eng.135, 416 (1939)

    Google Scholar 

  26. Avrami, M.: J. Chem. Phys.7, 1103 (1939);8, 212 (1940);9, 177 (1941)

    Google Scholar 

  27. Yinnon, H., Uhlmann, D.R.: J. Non-Cryst. Solids54, 253 (1983)

    Google Scholar 

  28. Kemeny, T., Granasy, L.: J. Non-Cryst. Solids68, 193 (1984)

    Google Scholar 

  29. Criado, J.M., Ortega, A.: J. Non-Cryst. Solids87, 302 (1986)

    Google Scholar 

  30. Gao, Y.Q., Wang, W.: J. Non-Cryst. Solids81, 129, 135 (1986)

    Google Scholar 

  31. Henderson, D.W.: J. Non-Cryst. Solids30, 301 (1979)

    Google Scholar 

  32. Meisel, L.V., Cote, P.J.: Acta Metall.31, 1053 (1983)

    Google Scholar 

  33. Cusido, J.A., Isalgue, A.: Phys. Status Solidi (a)90, 127 (1985)

    Google Scholar 

  34. Ozawa, T.: Polymer12, 150 (1971)

    Google Scholar 

  35. Bansal, N.P., Bruce, A.J., Doremus, R.H., Moynihan, C.T.: J. Non-Cryst. Solids70, 379 (1985)

    Google Scholar 

  36. Augis, J.A., Bennet, J.E.: J. Thermal Anal.13, 283 (1978)

    Google Scholar 

  37. Marseglia, E.I.: J. Non-Cryst. Solids41, 31 (1980)

    Google Scholar 

  38. Kissinger, H.E.: J. Res. Nat. Bur. Stand.57, 217 (1956)

    Google Scholar 

  39. Chen, H.S.: J. Non-Cryst. Solids27, 257 (1978)

    Google Scholar 

  40. Borchard, H.J.: J. Inorg. Nucl. Chem.12, 252 (1960)

    Google Scholar 

  41. Piloyan, G.O., Ryabchikov, I.D., Novikova, O.S.: Nature212, 1229 (1966)

    Google Scholar 

  42. Geller, W., Garbeck, H.: Arch. Eisenhüttenwes.26, 611 (1955)

    Google Scholar 

  43. Dietz, G., Holland-Moritz, D.: (to be published)

  44. Lisher, E., Wilkenson, C., Ericson, T., Häggström, L., Lundgren, L., Wäppling, R.: J. Phys. C7, 1344 (1974)

    Google Scholar 

  45. Predel, B., Fredel, M.: Arch. Eisenhüttenwes.42, 347 (1971)

    Google Scholar 

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  1. II. Physikalisches Institut, Universität zu Köln, Zülpicher Strasse 77, W-5000, Köln 41, Federal Republic of Germany

    G. Dietz & H. C. Schäfer

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  1. G. Dietz
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  2. H. C. Schäfer
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Dietz, G., Schäfer, H.C. The crystallization of Fe1−x P x , 0.09≦x≦0.26. Z. Physik B - Condensed Matter 86, 375–382 (1992). https://doi.org/10.1007/BF01323730

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  • DOI: https://doi.org/10.1007/BF01323730

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