Abstract
Starting from the extended SSH model that includes an external Coulomb potential arising from interchain charged solitons and counterions, the intrachain e-e interaction and the next neighbor hopping interactions, eight localized vibrational modes around the soliton lattice have been found for the doping levels from 3.33 at.% to 13.33 at.%. Among them three are infrared active and they can be used to interpret the three observed infrared absorption lines at 487, 1284 and 1362 cm−1. Furthermore, the frequencies of localized modes are decreased and their localizations are weakened when the dopant concentrations increase.
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Li, Z.J., An, Z. & Yao, K.L. The vibrational modes around the soliton lattice with next neighbor hopping interactions in highly doped trans-(CH) x . Z. Physik B - Condensed Matter 97, 499–502 (1995). https://doi.org/10.1007/BF01322430
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DOI: https://doi.org/10.1007/BF01322430