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EPR of radiation induced MoO 3-4 -centres in lead tungstate

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Zeitschrift für Physik B Condensed Matter

Abstract

Paramagnetic MoO 3-4 impurity centres are created in undoped PbWO4 single crystals by X-ray excitation at liquid nitrogen temperature. The Spin-Hamiltonian data of the axial electron-centre are discussed in a covalent model which takes into account contributions of cation states. Characteristic differences in EPR- and thermoluminescent features of PbWO4 with respect to other scheelite type tungstates can be explained in terms of the lead ion 6s 2-configuration.

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Authors and Affiliations

  1. I. Physikalisches Institut, Universität Giessen, Heinrich-Buff-Ring 16, D-6300, Giessen, Federal Republic of Germany

    A. Hofstaetter, A. Scharmann, D. Schwabe & B. Vitt

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  1. A. Hofstaetter
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  2. A. Scharmann
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  3. D. Schwabe
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  4. B. Vitt
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Part of thesis, Giessen 1977 (D26)

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Hofstaetter, A., Scharmann, A., Schwabe, D. et al. EPR of radiation induced MoO 3-4 -centres in lead tungstate. Z Physik B 30, 305–311 (1978). https://doi.org/10.1007/BF01320036

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  • DOI: https://doi.org/10.1007/BF01320036

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