Skip to main content
Log in

Untersuchungen zur Fehlordnung von NH4 Cl-Kristallen

Investigations of the defect order of NH4Cl-crystals

  • Published:
Zeitschrift für Physik B Condensed Matter

Abstract

Results of measurements of thedc andac-conductivity and of the thermally stimulated depolarization carried out on undoped, NiCl2-doped and NH3-saturated NH4Cl crystals respectively are reported. They give some information about the kind and properties of the point defects. They further show that the formation of defects depends even in the intrinsic range on the quantity of H2O adsorbed on the samples and that thedc andac conductivity are different at lower temperatures. These effects are to be attributed to the properties of the complex cation and to the special charge transport mechanism realized by a sequence of vacancy and proton jumps.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literatur

  1. Heneisen, J.D.: Thesis Clemson University 1972

  2. Kröger, A.F.: J. Chem. Phys.51, 4025 (1969)

    Google Scholar 

  3. Fuller, R.G., Patten, F.W.: J. Phys. Chem. Sol.31, 1539 (1970)

    Google Scholar 

  4. Harrington, T.M., Staveley, L.A.K.: J. Phys. Chem. Sol.25, 921 (1964)

    Google Scholar 

  5. Murti, Y.V.G.S., Murthy, C.S.N.: J. de Physique34, Suppl. C9–337 (1973)

    Google Scholar 

  6. Murti, Y.V.G.S., Prasad, P.S.: Sol. State Comm.15, 1619 (1974)

    Google Scholar 

  7. Heneisen, J.D., Lasker, A.L.: Phys. Lett.49 A, 369 (1974)

    Google Scholar 

  8. Boettcher, F., Spaeth, J.M.: phys. stat. sol. (b)61, 465 (1974) Boettcher, F.: Dissertationsarbeit, Universität Stuttgart 1973

    Google Scholar 

  9. Bittermann, K., Spaeth, J.M.: J. Crystal Growth21, 319 (1974)

    Google Scholar 

  10. Narayana, P.A., Venkateswarlu, P.: J. Chem. Phys.52, 5159 (1970)

    Google Scholar 

  11. Uebele, P.: Diplomarbeit, Universität Stuttgart 1973

  12. Kessler, A.: Proc. Symposium on Thermal and Photostimulated Currents, Dallas 5.–9. 10. 1975, im Druck

  13. Kessler, A., Caffyn, J.E.: J. Phys. C: Sol. State Phys.5, 1134 (1972)

    Google Scholar 

  14. Kessler, A.: Proc. Symposium on Thermal and Photostimulated Currents, Dallas 5.–9. 10. 1975, im Druck

  15. Bucci, C., Fieschi, R.: Phys. Rev.148, 816 (1966)

    Google Scholar 

  16. Kessler, A.: J. de Physique34, Suppl. C9–79 (1973)

    Google Scholar 

  17. Baker, H.B.: Hollemann-Wiberg, Lehrbuch d. Anorg. Chemie, S. 437

  18. Jacobs, P.W.M., Wee Lam NG: J. Phys. Chem. Solids33, 2031 (1972)

    Google Scholar 

  19. Harvey, P.J., Hoodless, I.M.: Phil. Mag.16, 543 (1967)

    Google Scholar 

  20. Murthy, C.S.N., Murti, Y.V.G.S.: J. Phys. C4, 1108 (1971)

    Google Scholar 

  21. Collin, J.: Mémoires de la Société Royale des Sciences Liège14 Fasc. 1 (1967)

  22. Chaiken, R.F., Sibbett, D.J., Sutherland, J.E., Van de Mark, D.K., Wheeler, A.: J. Chem. Phys.37, 2311 (1962)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berteit, P., Kessler, A. & List, T. Untersuchungen zur Fehlordnung von NH4 Cl-Kristallen. Z Physik B 24, 15–23 (1976). https://doi.org/10.1007/BF01312869

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01312869

Navigation