Abstract
A quantum-chemical study of the spatial and electronic structure of C-substituted aminophospha-alkenes and their cations has been carried out by the semi-empirical CNDO/BW method. Estimates are made of the relative stability of the cations as a function of the location of the added proton; the P-protonated cations are the most stable. The mechanism of protonation of the phospha-alkenes is discussed.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 25, No. 3, pp. 348–352, May–June, June, 1989.
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Pen'kovskii, V.V., Boldeskul, I.E. Quantum-chemical study of the protonation of aminophospha-alkenes. Theor Exp Chem 25, 323–327 (1989). https://doi.org/10.1007/BF01299013
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DOI: https://doi.org/10.1007/BF01299013