Abstract
Al-films were evaporated from Al2O3-crucibles or W-boats onto substrates held at 4.2 K or at room temperature (R.T.). The superconducting transition temperatureT c was measured in situ, while the oxygen contentC o of the films was determined by Rutherford-backscattering. Layers evaporated at R.T. from Al2O3-crucibles exhibit aT c vs.C o-relation like granular Al-films. For layers quench-condensed from W-boats without an external oxygen source typicalT c -values of 2.5 K and oxygen concentrations of 10 at % were found. In case of quench-condensation from Al2O3-crucibles it is concluded from theT c vs.C o-relation that oxygen is incorporated into the films in the form of Al2O-molecules. The different behavior of theT c vs.C o-curves will be discussed.
Similar content being viewed by others
References
Buckel, W., Hilsch, R.: Z. Phys.138, 109 (1954)
Bergmann, G.: Phys. Rep.27C. No. 4, 159–185 (1976)
Minnigerode, G. von, Rothenberg, J.: Z. Phys.213, 397 (1968)
Petit, R.B., Silcox, J.: Phys. Rev. B13, 2865 (1976)
Deutscher, G., Fenichel, H., Gershenson, M., Grünbaum, E., Ovadyahu, Z.: J. Low Temp. Phys.10, 231 (1973)
Cohen, R.W., Abeles, B.: Phys. Rev.168, 444 (1968)
Ziemann, P., Heim, G., Buckel, W.: Solid State Commun.27, 1131 (1978)
Ziemann, P., Meyer, O., Heim, G., Buckel, W.: Z. Phys. B—Condensed Matter35, 141 (1979)
Minnigerode, G. von: Z. Phys.154, 442 (1959)
Buck, V., Prüfer, G.: Verh. Dtsch. Phys. Ges.15, 395 (1980)
Brewer, L., Searcy, A.W.: J. Am. Chem. Soc.73, 5308 (1951)
Porter, R.F., Schissel, P., Inghram, M.G.: J. Chem. Phys.23, 339 (1955)
Farber, M., Srivastava, R.D., Uy, O.M.: J. Chem. Phys.55, 4142 (1971)
Drowart, J., Maria, G. De, Burns, R.P., Inghram, M.G.: J. Chem. Phys.32, 1366 (1960)
Knight, L.B., Jr., Weltner, W., Jr.: J. Chem. Phys.55, 5066 (1971)
Carty, M.: Al-Oxygen compounds. In: Main group elements: hydrogen and groups I–III. Lappert, M.F. (ed.), Inorganic chemistry series two, Vol. 1. London: Butterworth & Co. 1975
Leitz, H.: (private communication)
Prüfer, G.: Diplomarbeit, Universität Göttingen (1978)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nittmann, M., Ziemann, P., Buckel, W. et al. Dependence of the superconducting transition temperature of quench-condensed aluminium-films on the oxygen content. Z. Physik B - Condensed Matter 41, 205–209 (1981). https://doi.org/10.1007/BF01294423
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01294423