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Comparative study of the solid solutions in the ZrO2-HfO2-MgO(CaO) systems

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The specific features of the monoclinic-tetragonal transformation occurring in the ternary solid solutions of the ZrO2-HfO2-MgO(CaO) systems were presented.

The compounds CaZr4O9 and CaHf4O9 and the solid solutions based on them were studied.

A new (modified) form of an element of the phase diagram of the ZrO2-HfO2-CaO system was obtained on the basis of the results of our studies on the solid solutions present in the CaZr4O9-CaHf4O9 and CaZrO3-CaHfO3 systems.

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Literature cited

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Translated from Ogneupory, N. 3, pp. 3–5, March, 1991.

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Zoz, E.I., Karaulov, A.G. Comparative study of the solid solutions in the ZrO2-HfO2-MgO(CaO) systems. Refractories 32, 109–112 (1991). https://doi.org/10.1007/BF01290468

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