Abstract
This paper presents the results of an acidification experiment, consisting of seven consecutive equilibrations of repesentative soils of Galicia with a H2SO4 solution (pH 3). Different responses to soil acidification, such as SO4 retention and cation release, were evaluated. In soils derived from gabbro and amphibolite, SO4 retention and Al release were the principal acid neutralization mechanisms, whereas in soils derived from granite, schist, shale and sandstone Al release was the main process. The SO4 retention was significantly correlated with Al and Fe extracted with dihionite-citrate-bicarbonate and crystalline Fe. The released base cations came mainly from exchange sites, though sometimes also from other sources, probably by mineral weathering. The major sources of Al in these soils were metalorganic complexes and weatherable minerals. Solutions with pHs close to 4 are in equilibrium with gibbsite, kaolinite, jurbanite and alunite; at lower pH values, with jurbanite and alunite.
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Alvarez, E., Matinez, A., and Calvo, R.: 1992, ‘Geochemical Aspects of Aluminium in Forest Soils in Galicia (NW Spain)’,Biogechemistry (in press).
Bascomb, C. L.: 1968,J. Soil Sci. 19: 21.
Berden, M., Nilsson, S. J., Rosen, K., and Tyler, G.: 1987, Soil acidification-Extent, Cause and Consequences.National Swedish Environmental Protection Board, Solna, Sweden, pp. 164.
Billet, M. F., Parker-Jervis, F., Fitzpatrick, E. A., and Cresser, M. S.: 1990,J. Soil Sci. 41, 133.
Blakmore, L. C: 1978, ‘Exchange Complex Dominated by Amorphous Material (ECDAM)’, in G. D. Smith (ed.),The Andisol Proposal, 21. New Zealand.
Corey, R. B. and Jackson, M. C.: 1953.Anal. Chem. 25, 1233.
Dahlgren, R. A., AcAvoy, D. C., and Driscoll, C. T.: 1990,Environ. Sci. and Technol. 24, 531.
Dougan, W. R. and Wilson, A. L., 1974,Analyst 99, 413.
Fuller, R. D., David, M. B., and Driscoll, T.: 1985,Soil Sci. Soc. Amer. J. 49, 1034.
Giovanoli, R., Schnoor, S. L., Sigg, L., Stum, W., and Zobrist, J.: 1988,Clays Clay Miner. 36, 521.
Hegelson, H. C.; Garrels, R. M., and MacKenzie, F. P.; 1969,Geochim. Cosmochim. Acta 33, 455.
Hinghston, F. J.: 1982, ‘A. Review of Anion Adsorption’, in M. A. Anderson and A. J. Rubin (eds.),Adsorption of Inorganics at Solid-Liquid Interface. Ann Arbor Science, pp. 52–90.
Huete, A. R. and McColl, J. G.: 1984,J. Environ. Qual. 13, 366.
Jackson, M. L.: 1960, ‘Structural Role of Hydronium in Layer Silicates During Soil Genesis’,Transactions of the seventh International Congress of Soil Sciences,2, 445.
Juo, A. S. and Kamprath, E. J.: 1979,Soil. Sci. Soc. Amer. J. 43, 35.
Karathanasis, A. D., Evangelou, V. P., and Thompson, Y. L.: 1988,J. Environ. Qual. 17, 534.
Khanna, P. K., Prenzel, J., Meiwes, K.J., Ulrich, B., and Matzner, E.: 1987,Soil Sci. Soc. Amer. J. 51, 446.
Kharaka, Y. K., Gunter, D., Aggarwal, P. K., Perkins, E. H., and Debraal, D.: 1989, SOLMINEQ- 88: A computer program for geochemical Modeling of Water-Rock Interactions., U.S. Geological Survey. Menlo Park, California, pp. 420.
Lilieholm, B. C. and Feagley, S. E.: 1988,Soil Sci. 146, 44.
Louzao, M. J., Leiros, M. C., and Guitian, F.: 1990,Water, Air, and Soil Pollut. 49, 17.
May, H. M.; Helmke, P. A., and Jackson, M. L.: 1979,Geochim. Cosmochim. Acta 46, 681.
McDonald, N. W. and Hart, J. B.: 1990,Soil Sci. Soc. Amer. J. 54, 238.
Mehra, O. P. and Jackson, M. L.: 1960,Clays and Clay Minerals Proceedings Seventh Conference National Academy Science Natural Resources, Council Publication. Washington.
Nordstrom. D. K.: 1982,Geochim. Cosmochim. Acta 46, 681.
Nordstrom, D. K. and Ball, J. W.: 1986,Science 232, 54.
Nilsson, S. I. and Bergkvist, B.: 1983,Water, Air, and Soil Pollut. 20, 311.
Patill, S. G., Sarma, V. A. K., and Van Loon, G. W.: 1989,J. Soil Sci. 40, 85.
Peech, M., Alexander, L. T., Dean, L. A., and Reed, J. F.: 1947,Methods of Soil Analysis for Soil Fertility Investigations, U.S. Department Agriculture, pp. 757.
Reuss, J. O. and Johnson, D. W.: 1986,Acid Deposition and The Acidification of Soil and Waters, Springer-Verlag, New York.
Soil Survey Staff: 1975,Soil Taxonomy. Agricultural Handbook 436. Soil Conservation Service, USDA, Washington.
Süsser, P. and Schwertmann, V.: 1991,Geoderma 49, 63.
Ulrich, B.: 1983, in B. Ulrich and J. Pankrath (eds.),Effects of Accumulation of Air Pollutants in Ecosystems, D. Reidel Publ. Cam., Dordrecht, The Netherlands. pp. 127–146.
Urrutia, M., Garcia-Rodeja, E., and Macías, F.: 1988,Ann. Edafol. Agrobiol. 47, 131.
Urrutia, M., Garcia-Rodeja E., and Macías F.: 1991,Suelo y Planta 1, 399.
Walker, W. J., Cronan, C. S., and Bloom P. R.: 1990,Soil Sci. Soc. Amer. J. 54, 369.
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Merino, A., Alvarez, E. & Garcia-Rodeja, E. Response of some soils of Galicia (NW Spain) to H2SO4 acidification. Water Air Soil Pollut 74, 89–101 (1994). https://doi.org/10.1007/BF01257149
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DOI: https://doi.org/10.1007/BF01257149