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The oxidation state of manganese in its oxides and some other compounds, from the fine structure of the Kβ1β′-lines

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Summary

The X-ray Kβ1β′-emission spectra of the lower oxides of Mn have been studied. From this study it is concluded that Mn is present in the bi-, ter- and quadrivalent states in the oxides of apparently tervalent manganese, in approximately equal proportions.

Zusammenfassung

Aus den KKβ1β′-Linien der Röntgenemissionsspektren der niederen Manganoxide ergibt sich, daß das Mn in den Oxiden seiner scheinbar dreiwertigen Form in annähernd gleichen Mengenverhältnissen als Mn(II), Mn(III) und Mn(IV) vorliegt.

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References

  1. S. A. Stchukarev, State University of Leningrad Transactions 1945,197.

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Authors and Affiliations

  1. Laboratory of Non-stoichiometric Compounds, Department of Chemistry, State University of Leningrad, Leningrad, USSR

    Yu. P. Kostikov, T. G. Senichenkova, M. V. Loginova, N. S. Andrushenko, I. T. Sheftel & V. M. Polyanski

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  1. Yu. P. Kostikov
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  2. T. G. Senichenkova
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  3. M. V. Loginova
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  4. N. S. Andrushenko
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  5. I. T. Sheftel
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  6. V. M. Polyanski
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Kostikov, Y.P., Senichenkova, T.G., Loginova, M.V. et al. The oxidation state of manganese in its oxides and some other compounds, from the fine structure of the Kβ1β′-lines. Mikrochim Acta 66, 95–98 (1976). https://doi.org/10.1007/BF01257099

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  • DOI: https://doi.org/10.1007/BF01257099

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