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The infrared and Raman spectra of potassium azidopentacyanocobaltate(III) dihydrate: K3[Co(CN)5N3]·2H2O

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Abstract

Infrared spectra of potassium azidopentacyanocobaltate(III) dihydrate (PACDH) were obtained from the polycrystalline substance, both normal and deuterated, and from the monocrystal using in this case a polarization analyzer. Raman spectra of the normal powder were also obtained. The observed bands were assigned either to the internal vibrational modes of the azidopentacyanocobaltate(III) ion (AC) or to the internal and librational modes of the hydration water.

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References

  • Barca, R., Ellis, J., Tsao, M., and Wilmarth, W. K. (1967)Inorg. Chem. 6, 243.

    Google Scholar 

  • Basolo, F., and Hammaker, G. S. (1960)J. Am. Chem. Soc. 82, 1001.

    Google Scholar 

  • Basolo, F., and Hammaker, G. S. (1962)Inorg. Chem. 1, 1.

    Google Scholar 

  • Berglund, B., Lindgren, J., and Tegenfeldt, J. (1978)J. Mol. Struct. 43, 179 (1978).

    Google Scholar 

  • Brun, G. (1968)Rev. Chim. Min. 5, 899.

    Google Scholar 

  • Bryant, J. I. (1963)J. Chem. Phys. 38, 2845.

    Google Scholar 

  • Castellano, E. E., Piro, O. E., Punte, G., Amalvy, J. I., Varetti, E. L., and Aymonino, P. J. (1982)Acta Crystallogr. B 38, 2239.

    Google Scholar 

  • Cotton, F. A., (1967)Chemical Applications of Group Theory (Interscience, New York).

    Google Scholar 

  • Della Védova, C. O., Lesk, J. H., Varetti, E. L., Aymonino, P. J., Piro, O. E., Rivero, B. E., and Castellano, E. E. (1981)J. Mol. Struct. 70, 241.

    Google Scholar 

  • Druding, L. F., Wang, H. C., Cohen, R. E., and Sancilio, F. D. (1973)J. Coord. Chem. 3, 105 (1973).

    Google Scholar 

  • Falk, M., and Knop, O. (1973) InWater. A Comprehensive Treatise, Vol. 2, F. Franks, ed. (Plenum Press, New York), Chapter II.

    Google Scholar 

  • Forster, D., and Harrocks, W. D. (1966)Inorg. Chem. 5, 1510.

    Google Scholar 

  • Gutterman, D. F., and Gray, H. B. (1971)J. Am. Chem. Soc. 93, 3364.

    Google Scholar 

  • Holzbecher, M., Knop, O., and Falk, M. (1971)Can. J. Chem. 49, 1413.

    Google Scholar 

  • Linhard, M., and Flygare, H. (1950)Z. Anorg. Allg. Chem. 262, 328.

    Google Scholar 

  • Nakagawa, I., and Shimanouchi, T. (1962)Spectrochim. Acta 18, 101.

    Google Scholar 

  • Nakamoto, K. (1978)Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley-Interscience, New York), 3th edn.

    Google Scholar 

  • Nazarenko, Y. P., Zhilinskaya, V. V., Koslov, G. A., and Yatsimirskii, K. B. (1978)Russ. J. Inorg. Chem. 23, 1963.

    Google Scholar 

  • Olabe, J. A., and Aymonino, P. J. (1980) Fifteenth Argentine Chemical Meeting, Horco Molle, San Miguel de Tucumán, September 17–20.

  • Rigotti, G. E., Aymonino, P. J., and Varetti, E. L. to be published.

  • Swanson, B. I., and Jones, L. H. (1971)J. Chem Phys. 55, 4174.

    Google Scholar 

  • Swanson, B. I., and Jones, L. H. (1974)Inorg. Chem. 13, 313.

    Google Scholar 

  • Varetti, E. L., and Aymonino, P. J. (1973)Inorg. Chim. Acta 7, 597.

    Google Scholar 

  • Varetti, E. L., and Aymonino, P. J. (1982)J. Mol. Struct. 79, 281.

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 Esquina 115, 1900, La Plata, Argentina

    J. I. Amalvy (Predoctoral fellow of CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas), Rep. Argentina), E. L. Varetti (Members of the Carrera del Investigador Científico, CONICET) & P. J. Aymonino (Members of the Carrera del Investigador Científico, CONICET)

  2. Instituto de Física e Química de Sao Carlos, Universidade de Sao Paulo, Caixa Postal 369, 13.560, Sao Carlos, S. P., Brasil

    E. E. Castellano

  3. Departamento de Física, Facultad de Ciencias Exactas, Universidad National de La Plata, 47 Esquina 115, 1900, La Plata, Argentina

    O. E. Piro (Members of the Carrera del Investigador Científico, CONICET) & G. Punte (Members of the Carrera del Investigador Científico, CONICET)

Authors
  1. J. I. Amalvy
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  2. E. L. Varetti
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  3. P. J. Aymonino
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  4. E. E. Castellano
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  5. O. E. Piro
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  6. G. Punte
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Amalvy, J.I., Varetti, E.L., Aymonino, P.J. et al. The infrared and Raman spectra of potassium azidopentacyanocobaltate(III) dihydrate: K3[Co(CN)5N3]·2H2O. Journal of Crystallographic and Spectroscopic Research 13, 107–125 (1983). https://doi.org/10.1007/BF01246580

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  • DOI: https://doi.org/10.1007/BF01246580

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