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Mass spectrometric analysis of ceramics after decomposition with elemental fluorine

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Abstract

The features of a combustion with elementary fluorine for the case of compact SiC ceramics and model substances for boron containing ceramics (H3BO3 and Na2B4O7) were investigated with the aim of their decomposition and analysis. On-line detection of the gaseous decomposition products by quadrupole mass spectrometry using electron impact ionisation was studied. Limitations by blanks and transport interferences were investigated. Standard addition as well as the isotope dilution technique were used for calibration in the case of B, C and W at the trace and major component level.

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Authors and Affiliations

  1. Max-Planck-Institut für Metallforschung Stuttgart, Laboratorium für Reinstoffanalytik, Bunsen-Kirchhoff-Strasse 13, D-44139, Dortmund, Federal Republic of Germany

    Heinrich Kipphardt, Rainer P. H. Garten & Günther Tölg

  2. Institut für Spektrochemie und angewandte Spektroskopie (ISAS), P.O. Box 10 13 52, D-44013, Dortmund, Federal Republic of Germany

    Heinrich Kipphardt & Günther Tölg

  3. MAN Dezentrale Energiesysteme, P.O. Box 10 21 20, D-86011, Augsburg, Federal Republic of Germany

    Eberhard Jacob

  4. Universität Dortmund, Fachbereich Chemie, P.O. Box 50 05 00, D-44227, Dortmund, Federal Republic of Germany

    José A. C. Broekaert

Authors
  1. Heinrich Kipphardt
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  2. Rainer P. H. Garten
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  3. Eberhard Jacob
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  4. José A. C. Broekaert
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  5. Günther Tölg
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Additional information

Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthday

Deceased May 1995.

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Kipphardt, H., Garten, R.P.H., Jacob, E. et al. Mass spectrometric analysis of ceramics after decomposition with elemental fluorine. Mikrochim Acta 125, 101–105 (1997). https://doi.org/10.1007/BF01246170

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  • DOI: https://doi.org/10.1007/BF01246170

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