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Laboratory investigation of annular denuders as sampling system for the determination of aliphatic primary and secondary amines in stack gas

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Abstract

A method for the sampling and analysis of aliphatic amines ranging from C1 to C5 and some diamines in exhaust gas is described. Two different annular denuder systems coated with phosphoric acid were used for the laboratory investigation of sampling gaseous amines. The denuder sampling systems were tested under different conditions for their readiness to work in stack gas.

The reagent 2,4-dinitrofluorobenzene (DNFB) was used in pre-column derivatization of the amines investigated. The amino derivatives were separated using high performance liquid chromatography (HPLC) in conjunction with UV-detection. This method has been used for the examination of emissions from a landfill waste disposal and from animal husbandry with respect to traces of aliphatic amine emissions.

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References

  1. P. K. Dasgupta,Anal. Chem. 1995,67, 468 A.

    Google Scholar 

  2. H. A. H. Billiet,J. Chromatogr. 1992,51, B583.

    Google Scholar 

  3. H. Kataoka, S. Ohrui, Y. Miyamoto, M. Makita,Biomed. Chromatogr. 1992,6, 251.

    PubMed  Google Scholar 

  4. H. Kataoka, M. Eda, M. Makita,Biomed. Chromatogr. 1993,7, 129.

    PubMed  Google Scholar 

  5. K. Mopper, R. O. Zika,Nature 1987,325, 246.

    Google Scholar 

  6. M. R. Lopez, M. J. G. Alvarez, A. J. M. Ordieres, P. T. Blanco,J. Chromatogr. A. 1996,721, 231.

    Google Scholar 

  7. T. Tsukioka, H. Ozawa, T. Murakami,J. Chromatogr. 1993,642, 395.

    Google Scholar 

  8. J. R. L. Smith, A. U. Smart, F. E. Hancock, M. V. Twigg,J. Chromatogr. 1991,547, 447.

    Google Scholar 

  9. F. Sacher, S. Lenz, H.-J. Brauch,J. Chromatogr. A. 1997,764, 85.

    Google Scholar 

  10. M. K. Abdul-Rashid, J. P. Riley, M. F. Fitzsimons, G. A. Wolff,Anal. Chim. Acta 1991,252, 223.

    Google Scholar 

  11. BASF, press report, Ludwigshafen 1997.

  12. X.-H. Yang, C. Lee, M. I. Scranton,Anal. Chem. 1993,65, 572.

    Google Scholar 

  13. G. M. Singer, W. Lijinsky,J. Agric. Food Chem. 1976,24, 553.

    PubMed  Google Scholar 

  14. G. Neurath, H. Ehmke, K.-H. Müller,Beiträge zur Tabakforschung. 1964,2, 321.

    Google Scholar 

  15. J. Ewender, O. Piringer,Dtsch. Lebensm.-Rdsch. 1991,87, 5.

    Google Scholar 

  16. B. Pfundstein, A. R. Tricker, R. Preussmann,J. Chromatogr. 1991,539, 141.

    PubMed  Google Scholar 

  17. R. V. Golovnya,IARC Sci. Publ. 1976,14, 237.

    PubMed  Google Scholar 

  18. G. M. Singer, W. Lijinsky,J. Agric. Food Chem. 1976,24, 550.

    PubMed  Google Scholar 

  19. J. Oehlenschläger,Arch. Lebensmittelhyg. 1989,40, 55.

    Google Scholar 

  20. G. L. Hutchinson, A. R. Mosier, C. E. Andre,J. Environ. Qual. 1982,11, 288.

    Google Scholar 

  21. G. W. Schade, P. J. Grutzen,J. Atmos. Chem. 1995,22, 319.

    Google Scholar 

  22. G. Dure, L. Weil,KfW-Mitteilungen 1978,3, 3.

    Google Scholar 

  23. F. Gagnaire, S. Azim, P. Bonnet, P. Simon, J. P. Guenier, J. Ceaurriz,J. Appl. Toxicol. 1989,9, 301.

    PubMed  Google Scholar 

  24. W. A. Glasson,Environ. Sei. Technol. 1979,13, 1145.

    Google Scholar 

  25. T. J. Kneip, J. M. Daisey, J. J. Solomon, R. J. Hershman,Science 1983,221, 1045.

    PubMed  Google Scholar 

  26. IARC Working Group,IARC Monographs 1982,28, 89.

    Google Scholar 

  27. D. Breuer,Staub-Reinhalt. Luft. 1995,55, 59.

    Google Scholar 

  28. J. Casado, A. Castro, M. A. Lopez-Quntela, F. M. Lorenzo- Barral,Bull. Soc. Chim. France 1987,3, 401.

    Google Scholar 

  29. P. Mende, B. Spiegelhalder, C. D. Wacker, R. Preussmann,Fd. Chem. Tox. 1989,27, 469.

    Google Scholar 

  30. Finlayson-Pitts, J. N. Pitts,Atmospheric Chemistry: Fundamentals and Experimental Techniques. Wiley & Sons, New York, 1986.

    Google Scholar 

  31. H. Kataoka, S. Shindoh, M. Makita,J. Chromatogr. A. 1996,723, 93.

    PubMed  Google Scholar 

  32. B. Hager, R. Niessner,Mikrochim. Acta. 1996,122, 35.

    Google Scholar 

  33. D. Breuer,Kautschuk, Gummi, Kunstsoffe 1993,46, 235.

    Google Scholar 

  34. G. Audunsson, J. A. Jönsson, L. Mathiasson,Am. Ind. Hyg. Assoc. J. 1989,50, 535.

    Google Scholar 

  35. L. Grönberg, P. Lövkvist, J. A. Jönsson,Chemosphere 1992,24, 1533.

    Google Scholar 

  36. W. Schade,Diploma thesis, Johannes Gutenberg-Universität Mainz, 1993.

  37. R. Lindahl, J.-O. Levin, K. Andersson,J. Chromatogr. 1993,643, 35.

    Google Scholar 

  38. R. Liekefeld, R. H. Schuster, G. Wünsch,Kautschuk, Gummi, Kunststoffe 1991,44, 514.

    Google Scholar 

  39. S. Fuselli, G. Benedetti, R. Mastrangelli,Atmos. Environ. 1982,16, 2943.

    Google Scholar 

  40. P. Ciccioli, G. Bertoni, E. Brancaleoni, R. Fratarcangeli, F. Bruner,J. Chromatogr. 1976,126, 757.

    PubMed  Google Scholar 

  41. M. Possanzini, V. Di Palo,Chromatographia. 1990,29, 151.

    Google Scholar 

  42. W. Fiddler, R. C. Doerr,J. AOAC Intern. 1993,76, 578.

    Google Scholar 

  43. S. Vatsala, V. Bansal, D. K. Tuli, M. M. Rai, S. K. Jain, S. P. Srivastava, A. K. Bhatnagar,Chromatographia. 1994,38, 456.

    Google Scholar 

  44. S. F. Patil, S. T. Lonkar,J. Chromatogr. 1992,600, 344.

    PubMed  Google Scholar 

  45. T. Hamano, Y. Mitsuhashi, Y. Matsuki,J. Chromatogr. 1980,790, 462.

    Google Scholar 

  46. T. Hamano, A. Hasegawa, K. Tanaka, Y. Matsuki,J. Chromatogr. 1979,779, 346.

    Google Scholar 

  47. M. Dalene, G. Skarping, H. Tinnerberg,Chromatographia 1994,38, 776.

    Google Scholar 

  48. R. Westerholm, H. Li, J. Almen,Chemosphere 1993,27, 1381.

    Google Scholar 

  49. Y. Nishikawa, K. Kuwata,Anal. Chem. 1984,56, 1790.

    Google Scholar 

  50. VDI,Richtlinie 2467: Messen der Konzentration primärer und sekundärer aliphatischer Amine mit der Hochleistungs-Flüs- sigkeits-Chromatographie (HPLC), VDI 2467, 1991.

  51. A. Teckentrup, D. Klockow,Anal. Chem. 1978,50, 1728.

    Google Scholar 

  52. G. O. Nelson,Controlled Test Atmospheres, Ann Arbor Science Publishers, Ann Arbor, 1980.

    Google Scholar 

  53. G. Kallinger, R. Nieβner,Fres. J. Anal. Chem. 1997,358, 687.

    Google Scholar 

  54. B. Gerchel, W. Jockei, G. Kallinger, R. Nieβner,Forschungsbericht 01-VQ 9310/6, Bundesministerium für Forschung und Technologie, Bonn 1997.

    Google Scholar 

  55. G. Kallinger, R. Niessner,J. Aerosol Sci. 1997,28S, 613.

    Google Scholar 

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  1. Institute of Hydrochemistry, Technical University of Munich, Marchioninistrasse, 17, D-81377, München

    Guido Kallinger & Reinhard Niessner

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  1. Guido Kallinger
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  2. Reinhard Niessner
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Kallinger, G., Niessner, R. Laboratory investigation of annular denuders as sampling system for the determination of aliphatic primary and secondary amines in stack gas. Mikrochim Acta 130, 309–316 (1999). https://doi.org/10.1007/BF01242921

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