Skip to main content
SpringerLink
Log in

A new method for selective preconcentration of tin

  • Original Papers
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

In this paper the method of co-precipitating ⩾ 10 μg of Sn(IV) with Be(II) from an ammoniacal medium is made highly selective by incorporating a ternary masking system: (a) NH2OH-NTA-EDTA or (b) H2O2-NTA-EDTA. It serves to preconcentrate Sn(IV) from a number of ionic species, especially from Nb(V), Ta(V) and Ti(IV) in mg or even cg amounts. System (a) is also effective for masking Th(IV) and U(IV), and (b) for Sb(III), Sb(V) and Ge(IV). Hence the two systems are complementary.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. L. Luke,Anal. Chim. Acta 1967,37, 97.

    Google Scholar 

  2. J. Cifka, O. Ryba, V. Suk, M. Malat,Collection Czech. Chem. Commun. 1956,21, 1418.

    Google Scholar 

  3. M. Murano, S. Miyazaki,Bunseki Kagaku 1966,15, 657.

    Google Scholar 

  4. K. L. Cheng,Chemist-Analyst 1961,50, 126.

    Google Scholar 

  5. H. Freiser,Chemist-Analyst 1962,51, 62.

    Google Scholar 

  6. Y. X. Ci,Candidate Thesis, Moscow State University, 1962.

  7. D. I. Ryabchikov,Zh. Anal. Khim. 1956,11, 658.

    Google Scholar 

  8. W. C. Johnson,Organic Reagents for Metals, Vol. 1, 5th. Ed., Hopkin & Williams, Chadwell Heath, 1955, p. 74.

    Google Scholar 

  9. H. Bode,Z. Anal. Chem. 1954,143, 182.

    Google Scholar 

  10. E. B. Sandell,Colorimetric Determination of Traces of Metals, 3rd. Ed., Interscience, New York, 1957, p. 852.

    Google Scholar 

  11. E. Upor, M. Mohai, Gy. Novak,Photometric Methods in Inorganic Trace Analysis, Elsevier, Amsterdam, 1985, p. 316.

    Google Scholar 

  12. Yu. A. Bankovsky, M. V. Vircavs, O. E. Veveris, A. R. Pelne, D. K. Vircava,Talanta 1987,34, 179.

    Google Scholar 

  13. E. Baumgärtel, P. Gärtner,Z. Anal. Chem. 1965,208, 417.

    Google Scholar 

  14. G. Bosse, E. Wunderlich,Erzmetall 1971,24, 537.

    Google Scholar 

  15. K. L. Cheng,Chemist-Analyst 1963,52, 12.

    Google Scholar 

  16. K. L. Cheng,Anal. Chem. 1961,33, 783.

    Google Scholar 

  17. R. Kageyama, Y. Endo, T. Tomori,Bunseki Kagaku 1965,14, 531.

    Google Scholar 

  18. R. Pribil,Analytical Applications of EDTA and Related Compounds, Pergamon, Oxford, 1972, pp. 63–70.

    Google Scholar 

  19. B. Bieber, Z. Vecera,Slévárenstivi 1957,4, 48.

    Google Scholar 

  20. H. Yaguchi, T. Kajiwara,Bunseki Kagaku 1965,14, 785.

    Google Scholar 

  21. E. Lassner,J. Less-Common Met. 1968,15, 143.

    Google Scholar 

  22. E. Lassner, H. Schedle,Talanta 1968,15, 623.

    Google Scholar 

  23. E. Lassner, R. Püschel,Mikrochim. Acta [Wien] 1963, 950.

  24. H. Ward, H. W. Lakin,Anal. Chem. 1954,26, 1168.

    Google Scholar 

  25. Yu. Yu. Lur'e,Spravochnik po Analiticheskoi Khimii, Khimiya, Moscow, 1979, p. 347.

    Google Scholar 

  26. K. L. Cheng, P. Lott,Anal. Chem. 1956,28, 462.

    Google Scholar 

  27. C. F. Hiskey, A. L. Batik,Anal. Chem. 1953,25, 823.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shanghai Research Institute of Materials, MMBEI PRC, Handan Road 99, 200437, Shanghai, People's Republic of China

    Nan Zhou

Authors
  1. Nan Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhou, N. A new method for selective preconcentration of tin. Mikrochim Acta 108, 303–309 (1992). https://doi.org/10.1007/BF01242441

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01242441

Key words

Search

Navigation