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Clays as architectural units at modified-electrodes

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Abstract

Since Ghosh and Bard [80] first established the field of clay-modified electrodes some 15 years ago, great strides have been made in understanding the nature of the clay structural units and their impact on transport of a variety of electroactive probes (anions, neutrals, small cations, large cations, and compounds with distributed charge). Great strides have also been made in understanding the nature of the layered material in creating access of interlayer sites (size, charge, iron content, pillaring, and organic tailoring). In the last five years several successful applications of clay-modified electrodes have been achieved. Given the explosive growth in tailoring and construction of novel clay structures it seems reasonable to predict further significant advances in applications involving clay-modified electrodes.

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References

  1. J. Wang, T. Matinez,Electroanalysis 1989,1, 176.

    Google Scholar 

  2. L. Hernandez, P. Hernandez, E. Lorenzo,Analyst 1988,113, 621.

    Google Scholar 

  3. J. M. Bolts, M. S. Wrighton,J. Am. Chem. Soc. 1978,100, 5257.

    Google Scholar 

  4. A. B. Bocarsly, E. G. Walton, M. S. Wrighton,J. Am. Chem. Soc. 1980,102, 3390.

    Google Scholar 

  5. K. Narita, P. Kaviratna, T. J. Pinnavaia,J. Chem. Comm. 1990,1, 60.

    Google Scholar 

  6. J. R. Butruille, T. J. Pinnavaia,Catal. Today 1992,14, 141.

    Google Scholar 

  7. V. K. Gobi, R. Ramaraj,J. Chem. Soc. Chem. Comm. 1992, 1436.

  8. D. Rong, K. I. Kim, T. E. Mallouk,Inorg. Chem. 1990,29, 1531.

    Google Scholar 

  9. D. Rong, T. E. Mallouk,Inorg. Chem. 1993,32, 1454.

    Google Scholar 

  10. J. F. Rusling, C.-N. Shi, S. L. Suib,J. Electroanal. Chem. 1988,169, 315.

    Google Scholar 

  11. P. K. Ghosh, A. W.-H. Mau, A. J. Bard,J. Electroanal. Chem. 1984,169, 315.

    Google Scholar 

  12. C. Shi, J. F. Rusling, Z. Wang, W. S. Willis, A. M. Winiecki, S. L. Sub,Langmuìr 1989,5, 650.

    Google Scholar 

  13. F.-R. F. Fan, A. J. Bard,J. Electrochem. Soc. 1986, 301.

  14. H. Inoue, H. Yoneyama,J. Electroanal. Chem. 1987,233, 291.

    Google Scholar 

  15. M. Ohtani, O. Ikeda,J. Electroanal. Chem. 1995,354, 311.

    Google Scholar 

  16. D. Audebert, C. Sanchez,J. Sol-Gel Sci. Tech. 1994,2, 809.

    Google Scholar 

  17. G. A. Ozin, A. Kuperman, A. Stein,Angew. Chem. Int. Ed. Engl. 1989,28, 359.

    Google Scholar 

  18. A.-P. Pereira-Ramos, R. Messina, J. Perichon,J. Electroanal. Chem. 1983,146, 157.

    Google Scholar 

  19. M. V. Susic,Electrochim. Acta. 1979,24, 535.

    Google Scholar 

  20. M. R. Overcash, A. L. McPeters, E. J. Donugherty, R. G. Carbonell,Env. Sci. Tech. 1991,25, 1479.

    Google Scholar 

  21. R. M. Quigley, F. Fernandez, E. Yanful, T. Helgason, A. Margaritis, J. L. Whitby,Can. Geotech J. 1987,24, 377.

    Google Scholar 

  22. V. E. Crooks, R. M. Quigley,Can. Geotech. J. 1984,21, 349.

    Google Scholar 

  23. Y. B. Acar,Civ. Eng. 1992,62, 58.

    Google Scholar 

  24. A. P. Shapiro, R. F. Probstein,Env. Sci. Tech. 1993,27, 283.

    Google Scholar 

  25. R. F. Probstein, R. E. Hicks,Science 1993,260, 498.

    Google Scholar 

  26. R. A. Jacobs, M. Z. Sengun, R. E. Hicks, R. F. Probstein,Environ. Sci. Health 1994,A29, 1933.

    Google Scholar 

  27. P. I. Reid, B. Dolan, S. Cliffe,Society of Petroleum Engineers Meeting, San Antonio, Tx, 1995, SPE 28960, 155.

  28. H. van Olphen,Clay Colloid Chemistry, Wiley, New York, 1963.

    Google Scholar 

  29. P. Labbe, G. Reverdy,Langmuir 1988,4, 419.

    Google Scholar 

  30. B. Brahimi, P. Labbe, G. Reverdy,Langmuir 1992,8, 1908.

    Google Scholar 

  31. K. Itaya, H.-C. Cheng, I. Uchida,Inorg. Chem. 1987,26, 624.

    Google Scholar 

  32. C. Mousty, S. Therias, C. Forano, J.-P. Besse,J. Electroanal. Chem. 1994,374, 63.

    Google Scholar 

  33. B. Keita, N. Dellero, L. Nadjo,J. Electroanal. Chem. 1991,302, 47.

    Google Scholar 

  34. B. Keita, A. Belhouari, L. Nadjo,J. Electroanal Chem. 1993,355, 235.

    Google Scholar 

  35. S. Therias, C. Mousty,Appl. Clay Sci. 1995,10, 147.

    Google Scholar 

  36. S. Swartzen-Allen, E. Majijevic,Chem. Rev. 1978,74, 3885.

    Google Scholar 

  37. W. Jones, M. Chibiwe, in:Pillared Layered Structures,Current Trends and Applications (I.V. Mitchell, ed.) 1990.

  38. K. Takaya,Proc. Sapporo Conference on the Chemistry of Clays and Clay Minerals, Sept., 1996, p. 76.

  39. B. Keita, A. Belhouari, L. Nadjo,J. Electroanal Chem. 1991,314, 345.

    Google Scholar 

  40. J. W. Stucki, D. Tessier,Clays Clay Miner. 1991,32, 137.

    Google Scholar 

  41. A. Fitch, Y. Wang, S. Park, M. Marganski, in:New Directions in Electroanalytical Chemistry (J. Leddy, R. M. Winghtman, ed.) The Electrochemical Soc., Pennington, NY, 1996, p. 248.

    Google Scholar 

  42. H. Van Olphen,The Handbook for Clay Materials and Other Non-Metal Minerals, Pergamon, NY, 1979, p. 19.

    Google Scholar 

  43. K. Itaya, H.-C. Chang, I. Uchida,Inorg. Chem. 1987,26, 624.

    Google Scholar 

  44. A. W. Adamson,Physical Chemistry of Surfaces, Wiley, Chichester, 1982, p. 245.

    Google Scholar 

  45. J. Israelachvili, G. E. Adams,Nature 1976,262, 774.

    Google Scholar 

  46. T. Kunitake,Proc. Sapporo Conference on the Chemistry of Clays and Clay Minerals, Sept., 1996, p. 1

  47. P. M. Rice,Pottery Analysis, A Sourcebook, University of Chicago Press, 1987, p. 103.

  48. S. A. Lee, A. Fitch,J. Phys. Chem. 1990,94, 4998.

    Google Scholar 

  49. G. Brown,J. Soil Sci. 1953,4, 229.

    Google Scholar 

  50. G. Brown, G. W. Brindley, in:Crystal Sructures of Clay Minerals and Their X-ray Identification (G. W. Brindley, G. Brown ed.) Minerological Society, London, 1980, Chapter 5.

    Google Scholar 

  51. K. Norrish, J. A. Rausell-Colom,Clays Clay Miner. 1963,10, 123.

    Google Scholar 

  52. K. Norrish,Trans Faraday Soc. 1954,18, 120.

    Google Scholar 

  53. Y. Fukushima,Clays Clay Miner. 1984,32, 320.

    Google Scholar 

  54. J. A. Stein, A. Fitch,Anal. Chem. 1995,34, 1322.

    Google Scholar 

  55. S. M. Macha, A. Fitch, work in progress.

  56. A. Fitch, J. Du, H. Gan, J. W. Stucki,Clays Clay Miner. 1995,43, 607.

    Google Scholar 

  57. A. Fitch, R. J. Krzysik,J. Electroanal. Chem. 1993,379, 129.

    Google Scholar 

  58. B. M. Choudary,Proc. Sapporo Conference on the Chemistry of Clay and Clay Minerals, Sept., 1996, p. 8.

  59. L. Mercier, C. Detellier,Env. Sci. Tech. 1995,29, 1318.

    Google Scholar 

  60. P. Subramanian, A. Fitch,Env. Sci. Tech. 1992,26, 1775.

    Google Scholar 

  61. A. Fitch, J. Song, J. Stein,Clays Clay Miner. 1996,44, 370.

    Google Scholar 

  62. A. Fitch,Clays Clay Miner. 1990,38, 4, 391.

    Google Scholar 

  63. T. Okajima, T. Ohsaka, N. Oyama,J. Electroanal Chem. 1991,315, 175.

    Google Scholar 

  64. T. Okajima, T. Ohsaka, O. Hatozaki, N. Oyama,Electrochem. Acta. 1992,37, 1865.

    Google Scholar 

  65. A. Fitch, P. Subramanian,J. Electroanal. Chem. 1993,362, 111.

    Google Scholar 

  66. P. Joo, A. Fitch,Env. Sci. Tech. 1996,30, 2681.

    Google Scholar 

  67. A. Fitch, J. Du,J. Electroanal. Chem. 1991,319, 409.

    Google Scholar 

  68. J. A. Stein, A. Fitch,Clays Clay Miner. 1996,44, 381.

    Google Scholar 

  69. T. Wieglos, A. Fitch,Electroanalysis 1990,2, 449.

    Google Scholar 

  70. P. De S. Kaviratna, T. J. Pinnavaia,J. Electroanal. Chem. 1992,332, 135.

    Google Scholar 

  71. S. Park, A. Fitch,J. Phys. Chem. in press.

  72. A. Fitch, A. Lavy-Feder, S. A. Lee, M. T. Kirsh,J. Phys. Chem. 1988,92, 6665.

    Google Scholar 

  73. Y. Wang, A. Fitch, in preparation.

  74. A. Fitch, S. A. Lee,J. Electroanal. Chem. 1993,344, 45.

    Google Scholar 

  75. G. J. Edens, A. Fitch, A. Lavy-Feder,J. Electroanal. Chem. 1991,307, 139.

    Google Scholar 

  76. G. N. La Mar, G. R. Van Hecke,Inorg. Chem. 1973,12, 1767.

    Google Scholar 

  77. G. Villemure, A. J. Bard,J. Electroanal. Chem. 1990,282, 107.

    Google Scholar 

  78. R. D. King, D. G. Nocera, T. J. Pinnavaia,J. Electroanal. Chem. 1987,236, 443.

    Google Scholar 

  79. D. Petridis, P. Falaras, T. J. Pinnavaia,Inorg. Chem. 1992,31, 3530.

    Google Scholar 

  80. P. K. Ghosh, A. J. Bard,J. Am. Chem. Soc. 1983,105, 5691.

    Google Scholar 

  81. P. Labbe, B. Brahimi, G. Reverdy, C. Mousty, R. Blankespoor, A. Gautier, G. Deraud,J. Electroanal. Chem. 1994,1379, 103.

    Google Scholar 

  82. B. Brahimi, P. Labbe, G. Reverdy,J. Electroanal. Chem. 1989,267, 343.

    Google Scholar 

  83. W. E. Rudzinski, A. J. Bard,J. Electroanal. Chem. 1986,199, 323.

    Google Scholar 

  84. S. Yamanka, Y. Inoue, M. Hatori, F. Okumura, M. Yoshikawa,Bull. Chem. Soc. Jpn. 1992,65, 2494.

    Google Scholar 

  85. J. T. Lin, S. J. Jong, S. Cheng,Microporous Materials,1993,1(4), 287 (Amsterdam).

    Google Scholar 

  86. O. Enea, A. J. BardJ. Phys. Chem. 1986,90, 301.

    Google Scholar 

  87. P. Joo, G. A. Rafael, A. Fitch, S. Mellican, in:Nanoparticles in Solids and Solution. An Integrated Approach to their Preparation and Characterization (I. Dekany, M.-P. Pileni, J. H. Fendler, B. Vincent, eds.) Kluwer, Dordrecht, 1996, in press.

    Google Scholar 

  88. A. Galarneau, A. Barodawalla, T. J. Pinnavaia,Nature 1995,374, 529.

    Google Scholar 

  89. P. T. Tanev, M. Chibwe, T. J. Pinnavaia,Nature 1994,368, 321.

    PubMed  Google Scholar 

  90. P. T. Tanev, T. J. Pinnavaia,Science 1995,267, 865.

    Google Scholar 

  91. S. Therias, C. Mousty,Appl. Clay. Sci. 1995,10, 147.

    Google Scholar 

  92. M. Yamaguchi,Proc. Sapporo Conference on the Chemistry of Clays and Clay Minerals Sept., 1996, p. 69.

  93. N. Hu, J. F. Rusling,Anal. Chem. 1991,63, 2163.

    PubMed  Google Scholar 

  94. P. Falaras, D. Petridis,J. Electroanal. Chem. 1992,337, 229.

    Google Scholar 

  95. J. Qiu, G. Villemure,J. Electroanal.Chem. 1995,395, 159.

    Google Scholar 

  96. G. Villemure,Clays Clay Miner. 1996,44, 515.

    Google Scholar 

  97. Y Xiang, G. Villemure,J. Phys. Chem. 1996,100, 7143.

    Google Scholar 

  98. Y. Xiang, G. Villemure,Can. J. Chem. 1992,70, 1833.

    Google Scholar 

  99. P. Komadel, P. R. Lear, J. W. Stucki,Clays Clay Miner. 1990,38, 203.

    Google Scholar 

  100. C. M. Castro-Acuña, F.-R. F. Fan, A. J. Bard,J. Electroanal. Chem. 1987,234, 347.

    Google Scholar 

  101. P. Joo,Colloids and Surfaces 1990,49, 29.

    Google Scholar 

  102. H. Nijs, M. I. Cruz, J. J. Fripiat, H. Van Damme,N. J. De Chimie 1982,6, 11, 551.

    Google Scholar 

  103. P. V. Kamat,J. Electroanal. Chem. 1984,163, 389.

    Google Scholar 

  104. S. A. John, K. V. Gobi, A. Ramasubbu, R. Ramaraj,Research in Chemical Intermediates 1992,18, 203.

    Google Scholar 

  105. G. Villemure, C. Detellier, A. G. Szabo,Langmuir 1991,7, 1215.

    Google Scholar 

  106. J. R. White, A. J. Bard,J. Electroanal. Chem. 1986,197, 233.

    Google Scholar 

  107. M. T. Carter, A. J. Bard,J. Electroanal. Chem. 1987, 191.

  108. L. Margulies, H. Rozen, S. Nir,Clays Clay Miner. 1988,36, 270.

    Google Scholar 

  109. G. Rytwo, C. Serban, S. Nir, L. Margulies,Clays Clay Miner. 1991,39, 551.

    Google Scholar 

  110. K. V. Gobi, R. Ramaraj,J. Electroanal. Chem. 1994,368, 77.

    Google Scholar 

  111. J.-M. Zen, C.-W. Lo,Anal. Chem. 1996,68, 2635.

    Google Scholar 

  112. J. F. Rusling,Acc. Chem. Res. 1991,24, 75.

    Google Scholar 

  113. B. Ogorevc, X. Cai, I. Grabec,Anal. Chim. Acta 1995,305, 176.

    Google Scholar 

  114. I. G. Svegl, B. Ogorevc, V. Hudnik,Fresenius J. Anal. Chem. 1996,354, 770.

    Google Scholar 

  115. K. Kalcher, I. Grabec, G. Raber, X Cai, G. Tavcar, B. Ogorevc,J. Electroanal. Chem. 1995,386, 149.

    Google Scholar 

  116. G. Villemure,Clays Clay Miner. 1996,38, 622.

    Google Scholar 

  117. P. V. Kamat, K. R. Gopidas, T. Mukherjee, V. Joshi, D. Kotkar, V. S. Patnak, P. K. Ghosh,J. Phys. Chem. 1991,95, 10009.

    Google Scholar 

  118. V. Joshi, D. Kotkar, P. K. Ghosh,Proc. Indian Acad. Sci. 1990,102(3), 203.

    Google Scholar 

  119. A. Yamagishi, M. Soma,J. Am. Chem. Soc. 1981,103, 4640.

    Google Scholar 

  120. M. Tanigushi, A. Yamagishi, T. Iwamoto,Inorg. Chem. 1991,30, 2462.

    Google Scholar 

  121. A. Yamagishi, A. Aramata,J. Chem. Soc. Chem. Commun. 1984, 452.

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Macha, S.M., Fitch, A. Clays as architectural units at modified-electrodes. Mikrochim Acta 128, 1–18 (1998). https://doi.org/10.1007/BF01242184

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