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Indirect determination of perchlorate by atomic absorption spectrometry

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Abstract

A liquid-liquid extraction and determination of perchlorate by atomic absorption spectrometry is described. The method involves extraction of perchlorate with the Schiffs base complex [Co(BPTC)2]+, where BPTC = 2-benzoyl pyridine thiosemicarbazone, in methyl isobutyl ketone in acidic medium and subsequent analysis of cobalt in flame AAS, hence indirectly for perchlorate. The extraction efficiency is 98%. The calibration graph was found to be linear for 1.0–11.4 μg ClO −4 per ml of solvent, and the limit of detection is 30 ng ml−1. The present method is free from interference of large number of foreign ions. The method has been applied for determination of perchlorate in human blood serum samples spiked with perchlorate, urine and commercial potassium chlorate sample.

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References

  1. [1]I. Iwasaki, S. Utsami, C. Kang,Bull. Chem. Soc. Jpn. 1963,36, 25.

    Google Scholar 

  2. A. G. Fogg, C. Burgess, D. Thorburn Burns,Analyst 1971,96, 854.

    Google Scholar 

  3. D. Thorburn Burns, N. Chimpalee, M. Hariott,Anal. Chim. Acta. 1989,217, 177.

    Google Scholar 

  4. Y. Yamamoto, N. Okamoto, E. Tao,Anal. Chim. Acta 1969,47, 127.

    Google Scholar 

  5. W. J. Collinson, D. Boltz,Anal. Chem. 1968,40, 1896.

    Google Scholar 

  6. M. Valcarcel, F. Pino,Ann. Quim. 1972,68, 385.

    Google Scholar 

  7. M. Gallego, M. Valcarcel,Anal. Chim. Acta 1985,169, 161.

    Google Scholar 

  8. M. Geissler, R. Kunze,Anal Chim. Acta 1986,189, 245.

    Google Scholar 

  9. D. Thorburn Burns, P. Hanprasopwattana,Anal. Chim. Acta 1980,118, 185.

    Google Scholar 

  10. J. A. Weiss, J. B. Stanbury,Anal. Chem. 1972,44, 619.

    PubMed  Google Scholar 

  11. K. De, A. K. Guha,Indian J. Chem. 1990,29A, 605.

    Google Scholar 

  12. J. Bassett, R. C. Denney, G. H. Jeffery, J. Mendham (eds.),Vogel's Textbook of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis, 4th Ed., ELBS and Longmans, New York, 1978, pp. 324, 498.

    Google Scholar 

  13. R. L. Dutta, K. De,Indian J. Chem. 1988,27A, 133.

    Google Scholar 

  14. ACS Committee on Environmental Improvements, Guidelines for Data Acquisition and Data Quality Evaluation in Environmental Chemistry,Anal. Chem. 1980,52, 2241A.

    Google Scholar 

  15. J. B. Wyngaarden, B. M. Wright, P. Ways,Endocrinology 1952,50, 537.

    PubMed  Google Scholar 

  16. A. F. Godley, J. B. Stanbury,J. Clin. Endocrinol. 1954,14, 70.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, The University of Burdwan, 713104, Burdwan, India

    Sarnath Chattaraj, Kuntala De & Arabinda K. Das

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  1. Sarnath Chattaraj
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  2. Kuntala De
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  3. Arabinda K. Das
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Chattaraj, S., De, K. & Das, A.K. Indirect determination of perchlorate by atomic absorption spectrometry. Mikrochim Acta 106, 183–190 (1992). https://doi.org/10.1007/BF01242089

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  • DOI: https://doi.org/10.1007/BF01242089

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