Abstract
Band broadening in a large volume wall-jet cell electrochemical detector for liquid chromatography has been studied. Two regimes of stable operation were found which correlated well with the formation of smooth flow patterns. Smooth flow is also found to be important for avoiding erroneous results caused by backmixing.
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References
G. Horvai, E. Pungor,Chromatography Forum 1987, 15.
P. T. Kissinger, C. Refshauge, R. Dreiling, R. N. Adams,Anal. Lett. 1973,6, 465.
R. S. Schwartz, K. O. David,Anal. Chem. 1985,57, 1362.
J. B. Kafil, H.-Y. Cheng, T. A. Last,Anal. Chem. 1986,58, 285.
A. Sauter, W. Frick,J. Chromat. 1984,297, 215.
K. Slis,J. Chromat. Sci. 1986,24, 321.
G. Horvai, T. Szepesváry, E. Pungor,Hung. Pat. 185 451, filed August 23, 1981.
Zs. Niegreisz, L. Szücs, J. Fekete, G. Horvai, E. Pungor,J. Chromat. 1984,316, 451.
J. Fekete, G. Horvai, L. Szücs, P. Sárkány, Zs. Niegreisz, K. Tóth, E. Pungor,Hung. Sci. Instr. 1985,59, 33.
H. Gunasingham, B. Fleet,Anal. Chem. 1983,55, 1409.
H. Gunasingham, B. T. Tay, K. P. Ang,Anal. Chem. 1984,56, 2422.
H. Gunasingham, B. T. Tay, K. P. Ang,J. Chromat. 1985,341, 271.
H. Gunasingham, B. T. Tay, K. P. Ang,Anal Chim. Acta 1985,176, 143.
T. Wolf, G. T. Fritz, L. R. Palmer,J. Chromat. Sci. 1981,19, 387.
J. M. Elbicki, D. M. Morgan, S. G. Weber,Anal. Chem. 1984,56, 978.
G. Horvai, J. Fekete, Zs. Niegreisz, K. Tóth, E. Pungor,J. Chromat. 1987,385, 25.
M. Váradi, Zs. Feher, E. Pungor,J. Chromat. 1974,90, 259.
B. Fleet, C. J. Little,J. Chromat. Sci. 1974,12, 747.
M. Váradi, M. Gratzl, E. Pungor,Anal. Chim. Acta 1986,83, 1.
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Szücs, L., Horvai, G., Fekete, J. et al. Band broadening in a wall-jet type electrochemical detector for liquid chromatography. Mikrochim Acta 96, 259–267 (1988). https://doi.org/10.1007/BF01236110
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DOI: https://doi.org/10.1007/BF01236110