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Synthesis and structural characterization of 2,6-bis-(N-methylenemorpholino)-4-ter-butylphenol

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Abstract

The crystal and molecular structure of the title compound, C20H32N2O3, has been determined from X-ray diffraction data using CuKα radiation (λ=1.5418 Å). The compound crystallizes in triclinic space groupP1¯ with a=8.828(1),b=18.680(1),c=6.272(2)Å, α=93.42(1), β=0.24(2), γ=77.93(1)°,V=1009.4(2)Å3, andZ=2. The structure was solved by direct methods and the full-matrix least-squares refinement leads the finalR-factor to 0.065 for 3481 observed reflections withI≥3σ(I). The phenyl ring is planar and the morpholino rings assume perfect “chair” conformation. The molecules are held together by van der Waals forces.

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Authors and Affiliations

  1. Department of Crystallography and Biophysics, University of Madras, Guindy campus, 600 025, Madras, India

    S. Shanmuga Sundara Raj, M. N. Ponnuswamy & G. Shanmugam

  2. Department of Inorganic Chemistry, University of Madras, Guindy campus, 600 025, Madras, India

    M. Kandaswamy

Authors
  1. S. Shanmuga Sundara Raj
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  2. M. N. Ponnuswamy
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  3. G. Shanmugam
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  4. M. Kandaswamy
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DCB Contribution No. 810.

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Shanmuga Sundara Raj, S., Ponnuswamy, M.N., Shanmugam, G. et al. Synthesis and structural characterization of 2,6-bis-(N-methylenemorpholino)-4-ter-butylphenol. Journal of Crystallographic and Spectroscopic Research 23, 607–610 (1993). https://doi.org/10.1007/BF01228773

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  • DOI: https://doi.org/10.1007/BF01228773

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