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Crystal and molecular structure of μ-oxobis[bis(dipropyl dithiophosphato) oxomolybdenum(V)]

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Abstract

The title compound is triclinic, space group P¯1,a=10.670(5)b=13.053(3),c=8.944(5) Å,α=100.18(3),β=92.16(4),γ=80.88(3)°,Z=1,V=1210.4 Å3, andR=0.043 for 2579 reflections. The molecule has two distorted octahedra sharing a corner occupied by an oxygen (bridging) atom, the Mo-Ob-Mo angle being 180°. The two molybdenum-oxygen bond lengths Mo-Ob (bridging) and Mo-O1, (terminal) are 1.92 and 1.62 Å, respectively. Except the Mo-S bondtrans to the terminal oxygen atom which has a bond length 2.81 Å, all other Mo-S bonds have an average length of 2.50 Å.

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, 302 004, Jaipur, India

    R. Ratnani, R. Bohra, G. Srivastava & R. C. Mehrotra

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  1. R. Ratnani
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  2. R. Bohra
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  3. G. Srivastava
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  4. R. C. Mehrotra
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Ratnani, R., Bohra, R., Srivastava, G. et al. Crystal and molecular structure of μ-oxobis[bis(dipropyl dithiophosphato) oxomolybdenum(V)]. Journal of Crystallographic and Spectroscopic Research 20, 541–544 (1990). https://doi.org/10.1007/BF01221894

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  • DOI: https://doi.org/10.1007/BF01221894

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