Abstract
A thermodynamic treatment of curved boundary layers is given which closely parallels the conventional theory of curved interfacial layers. The boundary analogs to the Gibbs adsorption isotherm and the Gibbs-Tolman-Koenig-Buff equation are derived.
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Research supported under NSF Grant #MPS73-04743-A01.
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Mandell, M.J., Reiss, H. Thermodynamics of curved boundary layers. J Stat Phys 13, 107–112 (1975). https://doi.org/10.1007/BF01221371
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DOI: https://doi.org/10.1007/BF01221371