Skip to main content
SpringerLink
Log in

A new method for the solvent extraction separation and photometric determination of palladium

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Summary

TBP has been used for the extraction of palladium(II) from hydrobromic acid medium and a simple extraction scheme developed for separation of palladium from Fe(III), Co(II), Ni(II), Ru(III), Rh(III), Ir(III), and Pt(IV). A spectrophotometric method is described for the determination of palladium with 1-phenyl-2-thiourea. The effects due to acidity, solvents, reagent concentration and diverse ions are reported. The complex is probably of 1 ∶ 1 composition.

Zusammenfassung

Tributylphosphat wurde zur Extraktion von Pd(II) aus bromwasserstoffsaurem Medium herangezogen und ein einfaches Verfahren zur Abtrennung des Pd von Fe(III), Co(II), Ni(II), Ru(III), Rh(III), Ir(III) und Pt(IV) daraus entwickelt. Die spektrophotometrische Bestimmung des Pd mit 1-Phenyl-2-thioharnstoff wurde beschrieben. Über den Einfluß der Acidität, der Lösungsmittel, der Reagenskonzentration und verschiedener Fremdionen wurde berichtet. Die Zusammensetzung des Komplexes entspricht wahrscheinlich dem Verhältnis 1∶1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. F. Peppard, W. J. Driscoll, R. J. Sirone, and S. McCarty, J. Inorg. Nucl. Chem.4, 326, (1957).

    Google Scholar 

  2. E. N. Pollock, Analyt. Chim. Acta47, 367, (1969).

    Google Scholar 

  3. G. H. Ayres and B. L. Tuffly, Analyt. Chemistry24, 949, (1952).

    Google Scholar 

  4. A. K. Majumdar and B. Sen, Analyt. Chim. Acta8, 369 (1953).

    Google Scholar 

  5. J. H. Yoe and A. L. Jones, Ind. Eng. Chem., Analyt. Ed.16, 111, (1944).

    Google Scholar 

  6. S. P. Patil and V. M. Shinde, Z. analyt. Chem.265, 349 (1973).

    Google Scholar 

  7. G. Charlot, Colorimetric Determination of Elements, 1st Ed. Amsterdam: Elsevier. 1964. p. 236.

    Google Scholar 

  8. G. Chariot, l. c. 7, p. 307.

    Google Scholar 

  9. E. B. Sandell, Colorimetric Determination of Traces of Metals, 3rd Ed., New York: Interscience. 1959. p. 783.

    Google Scholar 

  10. E. B. Sandell, l. c. 9. pp. 774, 520, 728.

    Google Scholar 

  11. O. Menis and T. C. Rains, Analyt. Chemistry27, 1932, (1955).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Shivaji University, Kolhapur-4, India

    S. P. Patil & V. M. Shinde

Authors
  1. S. P. Patil
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Shinde
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Patil, S.P., Shinde, V.M. A new method for the solvent extraction separation and photometric determination of palladium. Mikrochim Acta 62, 853–858 (1974). https://doi.org/10.1007/BF01218305

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01218305

Keywords

Search

Navigation