Summary
Palladium chloride was determined spectrophotometrically withβ-ethylthioethylenethioglycolic acid (β-ETETGA) and ethylene-bis-thioglycolic acid (EBTGA) in acid medium. The Pd-β-ETETGA system obeys Beer's law in the range 0.5–5.0μg/ml and Pd-EBTGA system obeys Beer's law in the range 0.4–8.0μg/ml. Determination of palladium in presence of many “associated metals” and many anions is reported.
Zusammenfassung
Palladiumchlorid läßt sich mitβ-Äthylthioäthylenthioglykolsäure bzw. mit Äthylen-bis-thioglykolsäure in saurem Medium spektralphotometrisch bestimmen. Das erstgenannte Reaktionssystem folgt zwischen 0,5 und 5,0μg Pd/ml, das andere zwischen 0,4 und 8,0μg Pd/ml dem Beerschen Gesetz. Über die Bestimmung von Pd in Gegenwart zahlreicher Begleitmetalle und vieler Anionen wurde berichtet.
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Pitombo, L.R.M., de Oliveira Neto, G. & de Oliveira, E. Analytical applications of thio-, seleno-, and telluroethers. VI. Mikrochim Acta 65, 121–128 (1976). https://doi.org/10.1007/BF01218256
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DOI: https://doi.org/10.1007/BF01218256