Skip to main content
SpringerLink
Log in

Simultaneous determination of sodium and potassium in human urine or serum using coated-wire ion-selective electrodes based on bis(crown ether)s

Simultane Bestimmung von Natrium und Kalium in menschlichem Harn oder Serum unter Verwendung ionen-selektiver Elektroden aus Bis-Kronen-Ethern

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Summary

High-performance coated-wire ion-selective electrodes based on dodecylmethyl bis(12-crown-4) and bis(benzo-15-crown-5) are used for the simultaneous determination of Na+ and K+ in human urine or serum by means of the Gran's plot method. The results of the potentiometric determination for Na+ and K+ in human urine or serum are in good agreement with the values obtained by flame photometry.

Zusammenfassung

Hochleistungsfähige ionen-selektive Elektroden auf der Basis von Dodecylmethyl-bis-(12-kronen-4)- und Bis-(benzo-15-kronen-5)-ether wurden für die simultane Bestimmung von Natrium und Kalium in menschlichem Harn bzw. Serum mit Hilfe von Gran's plot method verwendet. Die Ergebnisse der potentiometrischen Bestimmung stehen mit denen der Flammenphotometrie in guter Übereinstimmung.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Tamura, K. Kimura, and T. Shono, Analyt. Chemistry54, 1224 (1982).

    Google Scholar 

  2. T. Shono, M. Okahara, I. Ikeda, K. Kimura, and H. Tamura, J. Electroanal. Chem.132, 99 (1982).

    Google Scholar 

  3. K. Kimura, T. Maeda, H. Tamura, and T. Shono, J. Electroanal. Chem.95, 91 (1979).

    Google Scholar 

  4. H. Tamura, K. Kimura, and T. Shono, Bull. Chem. Soc. Japan53, 547 (1980).

    Google Scholar 

  5. H. Tamura, K. Kimura, and T. Shono, J. Electroanal. Chem.115, 115 (1980).

    Google Scholar 

  6. K. Kimura, H. Tamura, and T. Shono, J. Electroanal. Chem.105, 335 (1980).

    Google Scholar 

  7. H.-B. Jenny, C. Riess, D. Ammann, B. Magyar, R. R. Asper, and W. Simon, Mikrochim. Acta [Wien]1980 II, 309.

    Google Scholar 

  8. E. A. Mangubat, T. R. Hinds, and F. F. Vincenzi, Clin. Chem.24, 635 (1978).

    Google Scholar 

  9. A. Pelleg and G. B. Levy, Clin. Chem.21, 1572 (1975).

    Google Scholar 

  10. J. G. Schindler and M. von Gulich, J. Clin. Chem. Clin. Biochem.19, 49 (1981).

    Google Scholar 

  11. R. W. Cattrall and H. Freiser, Analyt. Chemistry43, 1905 (1971).

    Google Scholar 

  12. R. W. Cattrall, S. Tribuzio, and H. Freiser, Analyt. Chemistry46, 2223 (1974).

    Google Scholar 

  13. C. R. Martin and H. Freiser, J. Chem. Education57, 512 (1980).

    Google Scholar 

  14. C. R. Martin and H. Freiser, Analyt. Chemistry52, 562 (1980).

    Google Scholar 

  15. E. C. Horning, Organic Syntheses, Vol. III. New York: Wiley. 1955. p. 140.

    Google Scholar 

  16. E. Pungor, K. Toth, and A. H. Pall, Pure Appl. Chem.51, 1913 (1977).

    Google Scholar 

  17. G. Gran, Analyst77, 661 (1952).

    Google Scholar 

  18. T. S. Ma and S. S. M. Hassan, Organic Analysis Using Ion-Selective Electrodes, Vol. 1. London: Academic Press. 1982. p. 1630.

    Google Scholar 

  19. M. J. D. Brand and G. A. Rechnitz, Analyt. Chemistry42, 1172 (1970).

    Google Scholar 

  20. M. R. Truter, Structure and Bonding, Vol. XVI. Berlin-Heidelberg-New York: Springer-Verlag. 1973. p. 71.

    Google Scholar 

  21. K. Kimura, T. Tsuchida, T. Maeda, and T. Shono, Talanta27, 801 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, 565, Osaka, Japan

    H. Tamura, K. Kumami, K. Kimura & T. Shono

Authors
  1. H. Tamura
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Kumami
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Kimura
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Shono
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tamura, H., Kumami, K., Kimura, K. et al. Simultaneous determination of sodium and potassium in human urine or serum using coated-wire ion-selective electrodes based on bis(crown ether)s. Mikrochim Acta 80, 287–296 (1983). https://doi.org/10.1007/BF01213123

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01213123

Keywords

Search

Navigation