Abstract
Post-sintering treatments, such as zone melting under a thermal gradient, have been conducted on sintered YBCO tape cast films. YBCO precursor powder was derived through decomposition of a mixture of nitrates of cations in a microwave oven for ~ 4 min. The resulting powder was characterized and made into thin sheets by tape casting and then sintered at 945 °C for 5 h. The sintered tapes were subjected to repeated zone refining operations at the relatively high speed of ~ 30 mm h−1. A microstructure having uniformly orientated grains in thea-b plane throughout the bulk of the sample was obtained by three repeated zone refining operations. Details of precursor preparation, microwave processing and its advantages, zone refining conditions and microstructural features are presented in this paper.
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M. Leskela, C. H. Mueller, J. K. Truman andP. H. Holloway,Mater. Res. Bull. 23 (1988) 1477.
A. Manthiram andJ. B. Goodenough,Nature 329 (1987) 701.
S. Shibata, T. Kitagawa, H. Okazaki, T. Kimura andT. Murakami,Jpn. J. Appl. Phys. 27 (1988) L53.
H. K. Varma, K. G. K. Warrier andA. D. Damodaran,J. Amer. Ceram. Soc. 73 (1990) 3103.
J. Novch andT. Pelly,Mater. Res. Bull. 24 (1989) 283.
J. R. Spann, I. K. Lloyd, M. Kahn andM. T. Chase,J. Amer. Ceram. Soc. 73 (1990) 435.
U. Balachandran, R. B. Poeppel, J. E. Emerson, S. A. Johnson, M. T. Lanagan, C. A. Youngdahl, D. Shi, K. C. Goretta andN. G. Eror,Mater. Lett. 8 (1989) 454.
S. Jin,J. Metals 3 (1991) 7.
M. Murakami, M. Morita, K. Doi, K. Miyomoto andH. Hamada,Jpn. J. Appl. Phys. 28 (1989) L332.
S. Jin, R. C. Sherwood, T. H. Tiefel, R. B. Van Dover andT. Boone,J. Cryst. Growth 85 (1987) 639.
K. Salama, V. Selvamanickam, L. Gao andK. Sun,Appl Phys. Lett. 54 (1989) 2352.
R. L. Meng, C. Kinalidis, Y. Y. Sun, L. Gao, Y. K. Tao, P. H. Hor andC. W. Chu,Nature 345 (1990) 26.
P. J. McGinn, N. Zhu, W. Chen, M. T. Lanagan andU. Balachandran,Physica C 167 (1990) 343.
H. K. Varma, K. G. K. Warrier, A. Kumar, T. V. Mani, S. G. K. Pillai andA. D. Damodaran,Jpn. J. Appl. Phys. 31 (1992) L543.
P. Perumal, H. K. Varma, K. G. K. Warrier andA. D. Damodaran,Trans. J. Brit. Ceram. Soc. (1993) in press.
K. G. K. Warrier, H. K. Varma, T. V. Mani andA. D. Damodaran,J. Amer. Ceram. Soc. (1993) in press.
P. J. McGinn, W. Chen, N. Zhu andM. T. Lanagan,Physica C 165 (1990) 480.
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Warrier, K.G.K., Varma, H.K., Mani, T.V. et al. Zone refining of sintered, microwave derived YBCO superconductors. J Mater Sci 30, 3238–3241 (1995). https://doi.org/10.1007/BF01209243
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DOI: https://doi.org/10.1007/BF01209243