Skip to main content
SpringerLink
Log in

Spectrophotometric determination of beryllium in bronzes with Chrome Azurol S

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Summary

Spectrophotometric Determination of Beryllium in Bronzes with Chrome Azttrol S

Some remarks on the spectrophotometric determination of beryllium in bronzes using Chrome Azurol S (CAS) are given. The determination was performed at pH=6.5 and 10.0 using hexamethylene-tetramine and ammoniacal buffers, respectively. It was demonstrated that the determination of Be with CAS at pH=10.0 is slightly less sensitive, but it has two advantages which are important in obtaining reliable results. First, is the shorter time to reach the equilibrium between Be and CAS, and second, is lower pH sensitivity so that a better precision of the results at pH=10.0 overcompensate the slightly lower sensitivity at this pH in comparison with that at pH=6.5.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. J. Welcher (ed.), Standard Methods of Chemical Analysis, Princeton: Van Nostrand Comp. Inc. 1963.

    Google Scholar 

  2. J. Fries and H. Getrost, Organische Reagenzien für die Spurenanalyse, Darmstadt: E. Merck 1975.

    Google Scholar 

  3. J. H. Wood, Mikrochim. Acta [Wien]l, 11 (1955).

    Google Scholar 

  4. I. S. Mustafin and L. O. Matveev, Zavodsk. Lab.24, 259 (1958).

    Google Scholar 

  5. L. Silverman and M. E. Shideler, Anal. Chem.31, 152 (1959).

    Google Scholar 

  6. Y. Katsube, K. Uesugi, and J. H. Yoe, Bull. Chem. Soc. Japan34, 72 (1961).

    Google Scholar 

  7. L. P. Adamovich, O. V. Morgulj-Meschkova, and B. V. Jutzis, Zh. Anal. Khim.17, 676 (1962).

    Google Scholar 

  8. S. N. Sinha, and A. K. Dey, J. Indian Chem. Soc.39, 469 (1962).

    Google Scholar 

  9. P. Pakalns, Anal. Chim. Acta31, 576 (1964).

    Google Scholar 

  10. L. Sommer and V. Kuban, Coll. Czech. Chem. Commun.32, 4355 (1967).

    Google Scholar 

  11. L. Sommer and V. Kuban, Anal. Chim. Acta44, 333 (1969).

    Google Scholar 

  12. H. Nishida, T. Nishida, and H. Ohtomo, Bull. Chem. Soc. Japan49, 571 (1976).

    Google Scholar 

  13. S. Unemoto, Bull. Chem. Soc. Japan29, 845 (1956).

    Google Scholar 

  14. V. N. Tihonov and T. M. Anisimova, Zh. Anal. Khim.38, 778 (1983).

    Google Scholar 

  15. G. Kwapolinska and F. Buhl, Mikrochim. Acta [Wien]1, 333 (1984).

    Google Scholar 

  16. L. Meites, Handbook of Analytical Chemistry, New York: McGraw-Hill Comp. Inc. 1963.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Analytical Chemistry, Faculty of Technology, University of Zagreb, Zagreb, Yugoslavia

    I. Eškinja & Z. Grabarić

  2. Laboratory of General and Inorganic Chemistry, Faculty of Technology, University of Zagreb, Zagreb, Yugoslavia

    B. S. Grabarić

Authors
  1. I. Eškinja
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Grabarić
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. S. Grabarić
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eškinja, I., Grabarić, Z. & Grabarić, B.S. Spectrophotometric determination of beryllium in bronzes with Chrome Azurol S. Mikrochim Acta 86, 443–450 (1985). https://doi.org/10.1007/BF01206913

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01206913

Keywords

Search

Navigation