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Derivatives of imidazole as spectrophotometric analytical reagents

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Derivatives of Imidazole as Spectrophotometric Analytical Reagents

The synthesis, characteristics and metal-ion reactions of three imidazole derivatives, namely 4(5)-D-arabinotetrahydroxybutylimidazoline-2-thione (THBIT), and the oxime (IMALOX) and rhodanine (IMAR) of 4(5)-imidazolecarboxaldehyde, have been studied. IMALOX and IMAR exhibit three pK values in aqueous solution, but THBIT exhibits only one. All the reagents form stable complexes with only a small number of cations and some of them show promise as Spectrophotometric reagents.

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References

  1. N. C. Li, J. M. White, and E. Doody, J. Am. Chem. Soc.76, 6219 (1945).

    Google Scholar 

  2. J. E. Bauman and J. C. Wang, Inorg. Chem.3, 368 (1964).

    Google Scholar 

  3. F. Králík and J. Vřeštál, Coll. Czech. Chem. Commun.27, 1651 (1962).

    Google Scholar 

  4. T. Yoshimura and T. Ozaki, Bull. Chem. Soc. Japan52, 2268 (1979).

    Google Scholar 

  5. B. Lenarcik and B. Barszcz, Pol. J. Chem.53, 963 (1979).

    Google Scholar 

  6. J. Dehand and J. Jordanov, Inorg. Chim. Acta17, 37 (1976).

    Google Scholar 

  7. H. Sakurai and S. Takeshima, Transition Met. Chem.2, 103 (1977). 8 F. Holmes and F. Jones, J. Chem. Soc. 2398 (1960). 9 C. C. McDonald and W. A. Phillips, J. Am. Chem. Soc.85, 3736 (1966). 10 P. Brooks and N. Davidson, J. Am. Chem. Soc.83, 2118 (1960). 11 F. Schneider and W. Schaeg, Z. Physiol. Chem.326, 40 (1961). 12 F. Schneider and W. Schaeg, Z. Physiol. Chem.327, 74 (1962). 13 O. Yamauchi, M. Tanaka, and T. Uno, Chem. Pharm. Bull.14, 948 (1966). 14 O. Yamauchi, M. Tanaka, and T. Uno, Chem. Pharm. Bull.14, 952 (1966). 15 O. Yamauchi, M. Tanaka, and T. Uno, Talanta15, 177 (1968). 16 O. Yamauchi, M. Tanaka, and T. Uno, Talanta15, 459 (1968). 17 S. Shibata, M. Furukawa, and R. Nakashima, Anal. Chim. Acta81, 131 (1976). 18 H. Watanabe and N. Yamaguchi, Bunseki Kagaku28, 154 (1979). 19 S. Miwa, M. Furukawa, and S. Shibata, Anal. Chim. Acta120, 405 (1980). 20 L. E. Mattison, J. M. Metaxas, and C. S. O'Dell, Anal. Chem.41, 1690 (1969). 21 V. M. Dziomko, S. L. Zelichenok, and I. S. Markovich, Zh. Analit. Khim.18, 937 (1963). 22 E. B. Sandell and H. Onishi, Photometric Determination of Traces of Metals, 4th Ed., Part 1, General Aspects. New York: J. Wiley 1978. 23 K. V. Tserkasevich, P. O. Knizhko, and M. I. Mikhailenko, Zh. Analit. Khim.25, 532 (1970). 24 Yu. A. Zolotov, O. M. Petrukhin, V. Yu. Nagy, and L. B. Volodarskii, Anal. Chim. Acta115, 1 (1980). 25 V. Yu. Nagy, M. V. Evstiferov, O. M. Petrukhin, L. B. Volodarskii, and Yu. A. Zolotov, Anal. Chim. Acta128, 85 (1981). 26 H. Pauly and E. Ludwig, Z. Physiol. Chem.121, 170 (1922). 27 W. Hubball and F. L. Pyman, J. Chem. Soc. 25 (1928). 28 A. C. Davis and A. L. Levy, J. Chem. Soc. 2179 (1949). 29 D. D. Perrin and B. Dempsey, Buffers for pH and Metal Ion Control. London: Chapman & Hall 1979. 30 J. F. Bolaños, J. R. Cruz, and F, G. González, An. Quim. B.46, 501 (1950). 31 J. P. Phillips and L. L. Merritt, J. Am. Chem. Soc.70, 410 (1948). 32 W. Stenström and N. Goldsmith, J. Phys. Chem.30, 1683 (1926). 33 L. Sommer, Folia Fac. Sci. Nat, Univ. Purkynianae, Brno,5, l (1964). 34 K. L. Cheng, Anal. Chem.33, 783 (1961). 35 A. Lawson and H. V. Morley, J. Chem. Soc., 1103 (1956). 36 F. E. Piercy and D. E. Ryan, Can. J. Chem.41, 667 (1963). Correspondence and reprints: Dr. C. Fernández Pereira, Department of Chemistry, School of Industrial Engineering, University of Seville, Seville 41012, Spain.

    Google Scholar 

  8. F. Holmes and F. Jones, J. Chem. Soc. 2398 (1960).

  9. C. C. McDonald and W. A. Phillips, J. Am. Chem. Soc.85, 3736 (1966).

    Google Scholar 

  10. P. Brooks and N. Davidson, J. Am. Chem. Soc.83, 2118 (1960).

    Google Scholar 

  11. F. Schneider and W. Schaeg, Z. Physiol. Chem.326, 40 (1961).

    Google Scholar 

  12. F. Schneider and W. Schaeg, Z. Physiol. Chem.327, 74 (1962).

    Google Scholar 

  13. O. Yamauchi, M. Tanaka, and T. Uno, Chem. Pharm. Bull.14, 948 (1966).

    Google Scholar 

  14. O. Yamauchi, M. Tanaka, and T. Uno, Chem. Pharm. Bull.14, 952 (1966).

    Google Scholar 

  15. O. Yamauchi, M. Tanaka, and T. Uno, Talanta15, 177 (1968).

    Google Scholar 

  16. O. Yamauchi, M. Tanaka, and T. Uno, Talanta15, 459 (1968).

    Google Scholar 

  17. S. Shibata, M. Furukawa, and R. Nakashima, Anal. Chim. Acta81, 131 (1976).

    Google Scholar 

  18. H. Watanabe and N. Yamaguchi, Bunseki Kagaku28, 154 (1979).

    Google Scholar 

  19. S. Miwa, M. Furukawa, and S. Shibata, Anal. Chim. Acta120, 405 (1980).

    Google Scholar 

  20. L. E. Mattison, J. M. Metaxas, and C. S. O'Dell, Anal. Chem.41, 1690 (1969).

    Google Scholar 

  21. V. M. Dziomko, S. L. Zelichenok, and I. S. Markovich, Zh. Analit. Khim.18, 937 (1963).

    Google Scholar 

  22. E. B. Sandell and H. Onishi, Photometric Determination of Traces of Metals, 4th Ed., Part 1, General Aspects. New York: J. Wiley 1978.

    Google Scholar 

  23. K. V. Tserkasevich, P. O. Knizhko, and M. I. Mikhailenko, Zh. Analit. Khim.25, 532 (1970).

    Google Scholar 

  24. Yu. A. Zolotov, O. M. Petrukhin, V. Yu. Nagy, and L. B. Volodarskii, Anal. Chim. Acta115, 1 (1980).

    Google Scholar 

  25. V. Yu. Nagy, M. V. Evstiferov, O. M. Petrukhin, L. B. Volodarskii, and Yu. A. Zolotov, Anal. Chim. Acta128, 85 (1981).

    Google Scholar 

  26. H. Pauly and E. Ludwig, Z. Physiol. Chem.121, 170 (1922).

    Google Scholar 

  27. W. Hubball and F. L. Pyman, J. Chem. Soc. 25 (1928).

  28. A. C. Davis and A. L. Levy, J. Chem. Soc. 2179 (1949).

  29. D. D. Perrin and B. Dempsey, Buffers for pH and Metal Ion Control. London:Chapman & Hall 1979.

    Google Scholar 

  30. J. F. Bolaños, J. R. Cruz, and F. G. González, An. Quim. B.46, 501 (1950).

    Google Scholar 

  31. J. P. Phillips and L. L. Merritt, J. Am. Chem. Soc.70, 410 (1948).

    Google Scholar 

  32. W. Stenström and N. Goldsmith, J. Phys. Chem.30, 1683 (1926).

    Google Scholar 

  33. L. Sommer, Folia Fac. Sci. Nat, Univ. Purkynianae, Brno,5, 1 (1964).

    Google Scholar 

  34. K. L. Cheng, Anal. Chem.33, 783 (1961).

    Google Scholar 

  35. A. Lawson and H. V. Morley, J. Chem. Soc., 1103 (1956).

  36. F. E. Piercy and D. E. Ryan, Can. J. Chem.41, 667 (1963).

    Google Scholar 

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Fernández Pereira, C., Gasch Gómez, J. Derivatives of imidazole as spectrophotometric analytical reagents. Mikrochim Acta 86, 357–366 (1985). https://doi.org/10.1007/BF01206906

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