Abstract
A series of new transition metal complexes with the thiocyanate ion: (1) Mn(NCS)2·Benzo-15-crown-5, (2) Mn-(bipy)(NCS)2, (3) Ni(bipy)(NCS)2, prepared by using solution reaction methods, have been characterized by FT-IR spectra. The expression (I 2/I 1=tan2 θ) has been suggested to be used to calculate the bond angle N-metal-N (N atoms come from the two coordinating NCS groups) in the complexes.
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Lin, Y.Z., Wu, J.G. & Xu, G.X. FT-IR studies on the bonding mode of NCS groups in some new thiocyanate complexes. Mikrochim Acta 94, 219–221 (1988). https://doi.org/10.1007/BF01205874
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DOI: https://doi.org/10.1007/BF01205874