Skip to main content
SpringerLink
Log in

Trennung polychlorierter Biphenyle (PCB) durch RP-Flüssig-Chromatographie

Separation of polychlorinated benzenes (PCBz) and biphenyls (PCB) by reversed phase-liquid chromatography

  • Original Papers
  • Environmental analysis
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

The retention of 87 PCB congeners in the six RPLC systems Nucleosil C18/80% MeOH and 70% CH3CN, Sepralyte Diphenyl 70% MeOH and 55% CH3CN, Nucleosil 5 CN 47.5% McOH and 35% CH3CN is given as retention indices based on 2-ketoalkanes, and phenyl-alkanes for the phase Nucleosil 5 CN, respectively. The systems based on Nucleosil C18 gave the highest selectivity in PCB separation as demonstrated by the separation of the technical PCB mixtures. The LC fractions were analyzed by HRGC/EI-MSD. The polymeric C18 phase (Vydac 201 TP) gave a slightly different selectivity as compared to Nucleosil C18 with increased retention of congeners with a 4,4′ substitution. The systems based on Diphenyl and Nucleosil 5 CN favor the separation of the PCB according to the degree of chlorination.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hutzinger O, Safe S, Zitko V (1974) The chemistry of PCB's. CRC Press, Cleveland

    Google Scholar 

  2. Erickson MD (1986) Analytical chemistry of PCB's, Butterworth Publ, Boston

    Google Scholar 

  3. Ballschmiter K (1988) In: „Analytiker Taschenbuch”, Bd. 7, Springer Verlag, Berlin Heidelberg New York Tokyo

    Google Scholar 

  4. Ballschmiter K, Niemczyk R, Schäfer W, Zoller W (1987) Fresenius Z Anal Chem 328:583–587

    Google Scholar 

  5. Raff I (1987) Diplomarbeit, Universität Ulm

  6. Ballschmiter K, Zell M (1980) Fresenius Z Anal Chem 302:20–31

    Google Scholar 

  7. Mullin MD, Pochini CM, McCrindle S, Romhes M, Safe SH, Safe LM (1984) Environ Sci Technol 18:468–476

    Google Scholar 

  8. Ballschmiter K, Schäfer W, Buchert H (1987) Fresenius Z Anal Chem 326:253–257

    Google Scholar 

  9. Fischer R, Ballschmiter K (1988) Fresenius Z Anal Chem, in press

  10. Brinkman UATh, Seetz JW, Reymer HGM (1976) Chromatogr 116:353–363

    Google Scholar 

  11. Hanai T, Walton HF (1977) Anal Chem 49:1954

    Google Scholar 

  12. Brodsky J (1987) Thesis, Ulm; Brodsky J, Ballschmiter K (1988) Fresenius Z Anal Chem 331:295–301

  13. Baker JK (1979) Anal Chem 51:1693; Baker JK, Ma CY (1979) J Chromatogr 169:107

    Google Scholar 

  14. Schomburg G (1966) J Chromatogr 23:1

    Google Scholar 

  15. Sander LC, Wise SA (1987) Anal Chem 59:2309–2319

    Google Scholar 

  16. Sander LC, Wise SA (1988) J HRC + CC, 11:383–387

    Google Scholar 

  17. Swerev M, Ballschmiter K (1986) Chemosphere 15:1123–1126

    Google Scholar 

  18. Kaminsky LS, Fasco MJ (1979) J Chromatogr 155:363

    Google Scholar 

  19. Rapaport RA, Eisenreich SJ (1984) Environ Sci Technol 18:163–170

    Google Scholar 

  20. Cooke NHC, Olsen K (1980) J Chromatogr Sci 18:512

    Google Scholar 

  21. Vernell M, Dewaele C (1982) HRCC + CC 5:245

    Google Scholar 

  22. Issaq HJ, Klose J, Muschik M (1984) J Chromatgr 302:159–166

    Google Scholar 

  23. Ishii D, Takenchi T (1983) J Chromatogr 255:349–358

    Google Scholar 

  24. Zoller W, Schäfer W, Class Th, Ballschmiter K (1985) Fresenius Z Anal Chem 321:247–251

    Google Scholar 

Download references

Author information

Author notes

  1. J. Brodsky

    Present address: Battelle Institut, Am Römerhof 35, D-6000, Frankfurt, Bundesrepublik Deutschland

Authors and Affiliations

  1. Abteilung Analytische Chemie, Universität Ulm, Postfach 4066, D-7900, Ulm, Bundesrepublik Deutschland

    J. Brodsky & K. Ballschmiter

Authors
  1. J. Brodsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Ballschmiter
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Meinem Lehrer, Herrn Prof. Dr. G. Tölg in Verbundenheit und Freundschaft zum 60. Geburtstag gewidmet.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brodsky, J., Ballschmiter, K. Trennung polychlorierter Biphenyle (PCB) durch RP-Flüssig-Chromatographie. Z. Anal. Chem. 335, 817–825 (1989). https://doi.org/10.1007/BF01204095

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01204095

Search

Navigation