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Ion-exchange micro columns for on-line preconcentration of heavy metals I. A rapid voltammetric screening test of ion-exchange kinetics

Mikro-Ionenaustausch-Säulen für On-line-Anreicherung von Schwermetallen. I. Schneller voltammetrischer Screening-Test zur Ionenaustausch-Kinetik

  • Original Papers
  • Trace element analysis
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Summary

A screening test for the investigation of the kinetical behaviour of ion-exchange materials is described. The test enables to decide within a short time which resin may be suitable for a special preconcentration problem. It is based on voltammetric measurements carried out in a single vessel. Using Zn, Cd, Pb and Cu, seventeen ion-exchange materials were checked. Experimental conditions including pH, quantity and particle size of the resins were studied. With regard to water analysis the influence of Na, Ca, Mg, Zn and Fe was investigated. For the determination of the four trace elements in drinking water eight ion exchangers proved to be recommendable at pH 8.

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References

  1. Mizuike A (1983) Enrichment techniques for inorganic trace analysis. Springer, Berlin Heidelberg New York

    Google Scholar 

  2. Schwedt G (1988) Methoden der Spurenanreicherung anorganischer und organischer Stoffe aus Wässern, 2. Aufl. VogelVerlag, Würzburg

    Google Scholar 

  3. Nord L, Karlberg B (1981) Anal Chim Acta 125:199–202

    Google Scholar 

  4. Nord L, Karlberg B (1983) Anal Chim Acta 145:151–158

    Google Scholar 

  5. Fang Z, Shukun X, Suchun Z (1987) Anal Chim Acta 200:35–49

    Google Scholar 

  6. Olsen S, Pesseda LCR, Růžička J, Hansen EH (1983) Analyst 108:905–917

    Google Scholar 

  7. Malamas F, Bengtsson M, Johansson G (1984) Anal Chim Acta 160:1–10

    Google Scholar 

  8. Hartenstein SD, Růžička J, Christian GD (1985) Anal Chem 57:21–25

    Google Scholar 

  9. Schulze G, Elsholz O (1986) In: Welz B (ed) Fortschritte in der atomspektrometrischen Spurenanalytik, vol 2. VCH, Weinheim, pp 261–274

    Google Scholar 

  10. Schulze G, Elsholz O, Genthe W (1987) In: Welz B (ed) 4. Colloquium Atomspektrometrische Spurenanalytik. Bodenseewerk Perkin-Elmer, Überlingen, pp 187–196

    Google Scholar 

  11. Bilz J, Fröhlich P (1985) Z Phys Chem 266:495–504

    Google Scholar 

  12. Bilz J, Fröhlich P (1986) Z Phys Chem 267:661–666

    Google Scholar 

  13. Ambe F, Burba P, Lieser KH (1979) Fresenius Z Anal Chem 295:13–16

    Google Scholar 

  14. Lieser KH, Erboy M, Thybusch B (1987) Angew Makromol Chem 152:169–178

    Google Scholar 

  15. Lövkvist P, Jönsson JA (1987) Anal Chem 59:818–821

    Google Scholar 

  16. Firma E Merck (1984) Komplexometrische Bestimmungsmethoden mit Titriplex, Darmstadt

  17. Atkins PW (1986) Physical Chemistry, 3rd edn. Oxford University Press, Oxford

    Google Scholar 

  18. Lieser KH, Zuber G (1977) Angew Makromol Chem 57:183–194

    Google Scholar 

  19. Bysouth SR, Tyson JF, Stockwell PB (1988) Anal Chim Acta 214:329–337

    Google Scholar 

  20. Schulze G, Elsholz O (1989) Fresenius Z Anal Chem 333:740

    Google Scholar 

Download references

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, D-1000, Berlin 12

    G. Schulze & O. Elsholz

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  1. G. Schulze
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  2. O. Elsholz
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Dedicated to Prof. Dr. G. Tölg on the occasion of his 60th birthday

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Schulze, G., Elsholz, O. Ion-exchange micro columns for on-line preconcentration of heavy metals I. A rapid voltammetric screening test of ion-exchange kinetics. Z. Anal. Chem. 335, 721–727 (1989). https://doi.org/10.1007/BF01204076

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  • DOI: https://doi.org/10.1007/BF01204076

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