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Fast volatilization of some lanthanide and actinide elements from titanium surfaces

Schnelle Verflüchtigung einiger Lanthanidenund Aktinidenelemente von Titanoberflächen

  • Original Papers
  • Spectroscopic methods in materials research
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Summary

The ad- and desorption of trace quantities of the lanthanide elements lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, dysprosium, and ytterbium and of the actinide elements americium and curium were investigated by thermochromatographic and isothermal measurements with hot titanium columns. The adsorption enthalpies deduced from the experimental data are in reasonable agreement with calculated values which indicate considerable variations in volatility under such conditions. More volatile elements can quickly be separated from less volatile elements by heating the mixture on titanium in high vacuum.

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Author information

Authors and Affiliations

  1. Zentralinstitut für Kernforschung Rossendorf, DDR-8051, Dresden, Germany

    B. Eichler

  2. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, Germany

    C. Frink, N. Trautmann & G. Herrmann

  3. Gesellschaft für Schwerionenforschung, D-6100, Darmstadt, Germany

    G. Herrmann

Authors
  1. B. Eichler
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  2. C. Frink
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  3. N. Trautmann
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  4. G. Herrmann
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Additional information

Dedicated to Prof. Dr. G. Tölg on the occasion of his 60th birthday

Part of a Doctoral Thesis, Mainz 1987

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Eichler, B., Frink, C., Trautmann, N. et al. Fast volatilization of some lanthanide and actinide elements from titanium surfaces. Z. Anal. Chem. 335, 656–662 (1989). https://doi.org/10.1007/BF01204066

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  • DOI: https://doi.org/10.1007/BF01204066

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