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5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II)

5-Phenylazo-8-aminochinolin als empfindliches Reagens für die Extraktion und spektrophotometrische Bestimmung von Pd(II)

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Summary

The spectrophotometric determination of palladium(II) with 5-phenylazo-8-aminoquinoline (PAQ) is described. The method involves the formation of a Pd-APQ complex in dilute HCl solutions and the conversion of this complex into Pd(PAQ)2 by addition of NaOH. This latter complex is extracted into methyl isobutyl ketone and the absorbance is measured at 620 nm. The molar absorptivity is 7.9×104l·mole−1·cm−1. The method is applied to the determination of Pd(II) in catalysts.

Zusammenfassung

Die spektrophotometrische Bestimmung von Palladium (II) mit 5-Phenylazo-8-aminochinolin (PAQ) wurde beschrieben. Das Verfahren beinhaltet die Bildung eines Pd-PAQ-Komplexes in verdünnter Salzsäure und dessen Umsetzung in Pd(PAQ)2 durch Zugabe von Natronlauge. Dieser Komplex wird mit MIBK extrahiert und die Absorbanz bei 620 nm gemessen. Die molare Absorptivität beträgt 7,9×104l· mol−1·cm−1. Das Verfahren wurde zur Pd-Bestimmung in Katalysatoren benützt.

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References

  1. K. Burger, Organic Reagents in Metal Analysis. Oxford: Pergamon Press. 1973.

    Google Scholar 

  2. Z. Holzbecher, L. Diviš, M. Král, L. Sůcha, and F. Vláčil, Handbook of Organic Reagents in Inorganic Analysis. Chichester: Ellis Horwood. 1976.

    Google Scholar 

  3. V. K. Gustin and T. R. Sweet, Analyt. Chemistry36, 1674 (1964).

    Google Scholar 

  4. V. K. Gustin and T. R. Sweet, Analyt. Chemistry35, 1395 (1963).

    Google Scholar 

  5. V. K. Gustin and T. R. Sweet, Analyt. Chemistry37, 701 (1965).

    Google Scholar 

  6. K. Yamamoto, K. Ametami, and K. Amagao, Bunseki Kagaku16, 229 (1967).

    Google Scholar 

  7. Yu. A. Bankovskii, Latv. PSR Zinat, Akad. Vestis9, 115 (1965).

    Google Scholar 

  8. S. Maspoch, J. Bartrolí, and M. Blanco, Mikrochim. Acta [Wien]1983 III, 95.

    Google Scholar 

  9. V. K. Gustin and T. R. Sweet, Analyt. Chemistry35, 44 (1963).

    Google Scholar 

  10. M. Izquierdo, Thesis, Universidad Autónoma de Barcelona, 1982.

  11. A. I. Vogel, Textbook of Quantitative Inorganic Analysis, 3rd Ed., London: Longmans. 1963. p. 511.

    Google Scholar 

  12. E. V. Brown and J. J. Duffy, J. Organ. Chem.32, 1122 (1967).

    Google Scholar 

  13. F. R. Hartley, C. Burgess, and R. M. Alcock, Solution Equilibria. Chichester: Ellis Horwood. 1980.

    Google Scholar 

  14. Yu. A. Bankovskii and A. F. Ievinsh, Zh. Analit. Khim.13, 507 (1958).

    Google Scholar 

  15. E. R. Marhenke and E. B. Sandell, Analyt. Chim. Acta28, 259 (1963).

    Google Scholar 

  16. O. Menis and T. C. Rains, Analyt. Chemistry27, 1932 (1955).

    Google Scholar 

  17. R. S. Young, Analyst76, 49 (1951).

    Google Scholar 

  18. L. Bocanegra Sierra, J. A. Pérez Bustamante, and F. Burriel-Martí, Analyt. Chim. Acta59, 231, 249 (1972).

    Google Scholar 

  19. Z. Marczenko and M. Jarosz, Talanta28, 561 (1981).

    Google Scholar 

  20. K. L. Cheng and B. L. Goydish, Microchem. J.10, 158 (1966).

    Google Scholar 

  21. V. M. Ivanov, Zh. Analit. Khim.22, 763 (1967).

    Google Scholar 

  22. F. García Montelongo, V. González Diaz, and C. R. Tallo González, Analyst104, 1091 (1979).

    Google Scholar 

  23. A. Barba and M. Blanco, An. Quim.78, 344 (1982).

    Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Science, Autonomous University of Barcelona, Bellaterra (Barcelona), Spain

    M. Blanco & S. Maspoch

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  1. M. Blanco
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  2. S. Maspoch
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Blanco, M., Maspoch, S. 5-phenylazo-8-aminoquinoline as a sensitive reagent for the extraction-spectrophotometric determination of palladium(II). Mikrochim Acta 81, 11–20 (1983). https://doi.org/10.1007/BF01202674

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  • DOI: https://doi.org/10.1007/BF01202674

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