Skip to main content
SpringerLink
Log in

Catalysis

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

A brief summary of very recently published works on vibrational spectroscopic studies of adsorbed molecules (a) on metal single crystals or evaporated films with low surface area and (b) on supported metal catalysts or metal oxide catalysts with large surface area is presented here. So far as (a) is concerned some new results of EELS, reflection-absorption IR spectroscopy and IR emission spectroscopy (with cooled monochromator or interferometer) are discussed. With regards to topic (b) absorption by the support materials (SiO2, Al2O3, MgO, TiO2, etc.) usually prevents access to the region below about 1200 cm−1. Therefore we concentrate mainly on the methods (diffuse reflection, photoacoustic or emission spectroscopy) offering vibrational data in a wide frequency range. Some new developments in emission and FIR spectroscopy in our laboratory are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Sheppard, T. T. Nguyen, in:Advances in Infrared and Raman Spectroscopy, Vol. 5 (R. J. H. Clark, R. E. Hester, eds.), Heyden, London-Philadelphia-Rheine, 1978, chapt. 2.

    Google Scholar 

  2. C. L. Angell, in:Fourier Transform Infrared Spectroscopy, Vol. 3 (J. R. Ferrero, L. J. Basile, eds.), Academic Press, New York, 1982, chapt. 1.

    Google Scholar 

  3. J. G. Grasselli,Fourier Transform Infrared Spectroscopy, Industrial, Chemical and Biological Applications (T. Theophanides, ed.), Reidel, Dordrecht-Boston-Lancaster, 1984, pp. 55–82.

    Google Scholar 

  4. P. R. Griffiths, K. W. Van Every, N. A. Wright,Chemical, Biological and Industrial Applications of Infrared Spectroscopy (J. R. Durig, ed.), Wiley, Chichester-New York-Brisbane-Toronto-Singapore, 1985, pp. 253–275.

    Google Scholar 

  5. H. Ibach, D. L. Mills,Electron Energy Loss Spectroscopy and Surface Vibrations, Academic Press, New York, 1982.

    Google Scholar 

  6. R. Candano, J. M. Gilles, A. A. Lucas,Vibrations and Surfaces, Plenum, New York-London, 1982.

    Google Scholar 

  7. S. Lehwald, I. Ibach, J. E. Demuth,Surf. Sci. 1978,78, 577.

    Google Scholar 

  8. J. C. Bertolini, J. Rousseau,Surf. Sci. 1979,89, 467.

    Google Scholar 

  9. B. E. Koel, J. E. Crowell, B. E. Bent, C. M. Mak, G. Somorjai,J. Phys. Chem. 1986,90, 2949.

    Google Scholar 

  10. J. Demuth, P. N. Sanda, J. M. Warlaumont, J. C. Tsang, K. Christman,Vibrations at Surfaces (R. Candano, J. M. Gilles, A. A. Lucas, eds.), Plenum, New York-London, 1982.

    Google Scholar 

  11. J. Demuth, K. Christmann, P. N. Sanda,Chem. Phys. Lett. 1980,76, 201.

    Google Scholar 

  12. V. H. Grassian, E. L. Mutterties,J. Chem. Phys. 1987,91, 389.

    Google Scholar 

  13. M. Abon, J. C. Bertolini, J. Billy, J. Massardier, B. Tardy,Surf. Sci. 1985,162, 395.

    Google Scholar 

  14. R. G. Greenler,J. Chem. Phys. 1966,44, 310.

    Google Scholar 

  15. R. G. Greenler,J. Chem. Phys. 1969,50, 1963.

    Google Scholar 

  16. W. G. Golden, D. D. Saperstein, M. W. Severson, J. Overend,J. Phys. Chem. 1984,88, 574.

    Google Scholar 

  17. A. M. Bradshaw,Surf. Sci. 1985,158, 624.

    Google Scholar 

  18. M. A. Chesters,J. Electron Spectr. Rel. Phen. 1986,38, 123.

    Google Scholar 

  19. A. Crossley, D. A. King,Surf. Sci. 1977,68, 528.

    Google Scholar 

  20. A. Crossley, D. A. King,Surf. Sci. 1980,95, 131.

    Google Scholar 

  21. W. F. Banholzer, R. I. Masel,Surf. Sci. 1984,137, 339.

    Google Scholar 

  22. B. E. Hayden, A. M. Bradshaw,Surf. Sci. 1983,125, 787.

    Google Scholar 

  23. M. A. Chesters, S. F. Parker, R. Raval,Surf. Sci. 1986,165, 179.

    Google Scholar 

  24. M. A. Chesters, E. M. McCash,Surf. Sci. (accepted for publication).

  25. E. Langenbach, A. Spitzer, H. Luth,Surf. Sci. 1984,147, 179.

    Google Scholar 

  26. M. A. Chesters, S. F. Parker, R. Raval,J. Electron Spectr. Rel. Phen. 1986,39, 155.

    Google Scholar 

  27. B. E. Hayden, K. Prince, D. B. Woodruff, A. M. Bradshaw,Surf. Sci. 1983,133, 589.

    Google Scholar 

  28. W. G. Golden, C. Snyder, B. Smith,J. Phys. Chem. 1982,86, 4675.

    Google Scholar 

  29. D. D. Saperstein,Appl. Spectrosc. 1985,39, 615.

    Google Scholar 

  30. R. G. Nuzzo, D. L. Allara,J. Amer. Chem. Soc. 1983,105, 4481.

    Google Scholar 

  31. K. Kunimatsu, H. Seki, W. G. Golden,Chem. Phys. Lett. 1984,108, 195.

    Google Scholar 

  32. M. D. Baker, M. A. Chesters,Vibrations at Surfaces (R. Candano, J. M. Gilles, A. A. Lucas, eds.) Plenum, New York-London, 1982, p. 289.

    Google Scholar 

  33. N. D. S. Canning, M. A. Chesters,J. Electron Spectr. Rel. Phen. 1983,29, 69.

    Google Scholar 

  34. R. C. Greenler,Vibrations at Surfaces (R. Candano, J. M. Gilles, A. A. Lucas, eds.) Plenum, New York-London, 1982, p. 255.

    Google Scholar 

  35. S. Chiang, R. G. Tobin, P. L. Richards,J. Electron Spectr. Rel. Phen. 1983,29, 113.

    Google Scholar 

  36. S. Chiang, R. G. Tobin, P. L. Richards,J. Vac. Sci. Technol. 1984,A2, 1069.

    Google Scholar 

  37. S. Chiang, R. G. Tobin, P. L. Richards, P. A. Thiel,Phys. Rev. Lett. 1984,52, 648.

    Google Scholar 

  38. R. G. Tobin, S. Chiang, P. A. Thiel, P. L. Richards,Surf. Sci. 1984,140, 1984.

    Google Scholar 

  39. R. G. Tobin, P. L. Richards,Surf. Sci. 1987,179, 387.

    Google Scholar 

  40. M. Ito,Vibrations at Surfaces (R. Candano, J. M. Gilles, A. A. Lucas, eds.), Plenum, New York-London, 1982, p. 71.

    Google Scholar 

  41. T. Szilagyi,Appl. Surf. Sci. (to be published).

  42. D. M. Adams,Metal-Ligand and Related Vibrations, Arnold, London, 1967, p. 19.

    Google Scholar 

  43. J. Mink, A. Sarkany, P. Tetenyi,Izv. Khim. Comm. Dep. Chem. 1983,16, 140.

    Google Scholar 

  44. W. Krasser, H. Erwens, A. Fadini, A. J. Renouprez,J. Raman Spectr. 1980,9, 80.

    Google Scholar 

  45. I. M. Hamadeh, D. King, P. R. Griffiths,J. Catal. 1984,88, 264.

    Google Scholar 

  46. B. J. Medrum, J. C. Orr, C. H. Rochester,J. Chem. Soc. Chem. Comm. 1985, 1176.

  47. D. W. Vidrine, in:Fourier Transform Infrared Spectroscopy, Vol 3 (J. R. Ferraro, L. J. Basile, eds.), Academic Press, New York, 1982, p. 135.

    Google Scholar 

  48. J. B. Kinney, R. H. Staley,Anal. Chem. 1983,55, 343.

    Google Scholar 

  49. W. P. McKenna, S. Bandyopadhyay, E. M. Eyring,Appl. Spectrosc. 1984,38, 834.

    Google Scholar 

  50. G. Zachmann,J. Mol Struct. 1984,115, 465.

    Google Scholar 

  51. S. Bandyopadhyay, F. E. Massoth, S. Pons, E. M. Eyring,J. Phys. Chem. 1985,89, 2560.

    Google Scholar 

  52. N. Teramae, S. Tanaka,Anal. Chem. 1985,57, 95.

    Google Scholar 

  53. R. P. Eischens, S. A. Francais, W. A. Pliskin,J. Phys. Chem. 1956,60, 194.

    Google Scholar 

  54. N. Sheppard, J. Erkelens,Appl. Spectrosc. 1984,38, 471.

    Google Scholar 

  55. M. Primet, P. Fouilloux, B. Imelik,J. Catal. 1980,61, 553.

    Google Scholar 

  56. P. C. M. van Woerkom, R. L. de Grot,Appl. Optics 1982,21, 314.

    Google Scholar 

  57. J. Mink, T. Szilagyi, S. Wachholz, D. Kunath,J. Mol. Struct. 1986,142, 389.

    Google Scholar 

  58. P. L. Goggin, M. C. Norton, J. Mink,Inorg. Chim. Acta 1978,26, 125.

    Google Scholar 

  59. T. Szilagyi,Ph.D. Thesis, Budapest, 1978.

  60. M. Handke, N. J. Harrick,Appl. Spectr. 1986,40, 401.

    Google Scholar 

  61. M. A. Ford, R. A. Spragg,Appl. Spectr. 1986,40, 715.

    Google Scholar 

  62. B. Johnson, B. Rebenstorf, R. Larsson,Spectrosc. Lett. 1984,17, 473.

    Google Scholar 

  63. B. Johnson, B. Rebenstorf, R. Larsson, M. Primet,Appl. Spectr. 1986,40, 798.

    Google Scholar 

  64. L. M. Gratton, S. Paglia, F. Scattaglia, M. Cavallini,Appl. Spectr. 1978,32, 310.

    Google Scholar 

  65. P. J. Zanzucchi, M. W. Yim,Appl. Spectr. 1986,40, 1042.

    Google Scholar 

  66. D. A. Mantell, S. B. Ryali, G. L. Haller,Chem. Phys. Lett. 1983,102, 37.

    Google Scholar 

  67. Y. Nagasawa, A. Ishitani,Appl. Spectr. 1984,38, 168.

    Google Scholar 

  68. C. H. Peuker, K. Moeller, D. Kunath,J. Mol. Struct. 1984,114, 215.

    Google Scholar 

  69. M. D. Baker, J. Godber, G. A. Ozin,J. Phys. Chem. 1985,89, 2299.

    Google Scholar 

  70. M. D. Baker, G. A. Ozin, J. Godber,J. Phys. Chem. 1985,89, 305.

    Google Scholar 

  71. G. A. Ozin, M. D. Bader, K. Helwig, J. Godber,J. Phys. Chem. 1985,89, 1856.

    Google Scholar 

  72. M. D. Baker, J. Godber, G. A. Ozin,J. Am. Chem. Soc. 1985,107, 3033.

    Google Scholar 

  73. E. Knözinger, P. Hoffmann,Infrared Phys. 1984,24, 129.

    Google Scholar 

  74. J. Mink, P. L. Goggin (to be published).

Download references

Author information

Authors and Affiliations

  1. Institute of Isotopes of the Hungarian Academy of Sciences, P.O. Box 77, H-1525, Budapest, Hungary

    János Mink

Authors
  1. János Mink
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mink, J. Catalysis. Mikrochim Acta 93, 63–79 (1987). https://doi.org/10.1007/BF01201683

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01201683

Key words

Search

Navigation