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Crystal and molecular structure of cyclo-bisoxalyldecasulfur S10(CO)4

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Abstract

Cyclo-bisoxalyldecasulfur, S10(CO)4, is monoclinic:P21/n,a = 7.812(2),b = 7.273(2),c = 12.570(7) Å, β = 91.33 ° (4), andZ = 2. The structure was solved by direct methods from 942 nonequivalent four-circle diffractometer data and refined by least-squares methods toR(F) = 0.104 andR w(F) = 0.065. The mean S-S distance is 2.051 Å. The molecule is stabilized by intramolecular contact distances shorter than the sum of the van der Waals radii. The two S-(C-O)-C groups are planar, with an angle of 15 ° between them.

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Authors and Affiliations

  1. Institut für Kristallographie der Universität, Senckenberganlage 30, 6000, Frankfurt/M, Federal Republic of Germany

    J. W. Bats & H. Fuess

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  1. J. W. Bats
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  2. H. Fuess
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Bats, J.W., Fuess, H. Crystal and molecular structure of cyclo-bisoxalyldecasulfur S10(CO)4 . Journal of Crystal and Molecular Structure 9, 305–310 (1979). https://doi.org/10.1007/BF01200522

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