Summary
The crystal structure of tetrakis(N,N′-diallylthiourea)nickel(II) iodide [Ni(C7H12N2S)4I2] has been determined by a three-dimensional X-ray analysis. FinalR, after anisotropic least-squares refinement, is 8·8%. The crystals are tetragonal (P4/n):a = 11·24(1),c = 15·43(1) Å,Z = 2. Ni(II) is on a 4-fold axis; the coordination around it is flattened pyramidal and involves four sulphur atoms from four diallylthiourea molecules (Ni-S = 2·221 Å). Ni(II) is out of the plane through the sulphur atoms by 0·40 Å. Two I- ions lie on opposite sides with respect to the nickel atom along the 4-fold axis, at distances Ni...I(1) = 3·74 Å, Ni...I(2) = 6·64 Å. The orientation of the allylthiourea molecules is determined mainly by a hydrogen bond formed by one nitrogen (N(1)) with the iodine which is nearer to the nickel.
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Andreetti, G. D., Cavalca, L. & Musatti, A. (1968)Acta Crystallogr. B24, 683.
Berta, D. A., Spofford, III, W. A., Boldrini, P. & Amma, E. L. (1970)Inorg. Chem. 9, 136.
Calzolari Capacchi, L. & Fava Gasparri, G. (1970) Private communication.
Cavalca, L., Chiesi Villa, A., Mangia, A. & Palmieri, C. (1970)Inorg. Chim. Acta,4, 463.
Cavalca, L., Domiano, P., Fava Gasparri, G. & Boldrini, P. (1967)Acta Crystallogr. 22, 878.
Dragonette, K. S. & Karle, I. L. (1965)Acta Crystallogr. 19, 978.
Fava Gasparri, G., Nardelli, M. & Villa, A. (1967)Acta Crystallogr. 23, 384.
Immirzi, A. (1967)Ric. Sci. 37, 743.
Kunchur, N. R. & Truter, M. R. (1958)J. Chem. Soc. 3478.
Moore, F. H. (1963)Acta Crystallogr. 16, 1169.
Okaya, Y. & Knobler, C. B. (1964)Acta Crystallogr. 17, 928.
Sirigu, A. (1969)Chem. Comm. 256.
Sirigu, A. (1970)Inorg. Chem. 9, 2245.
Tarantelli, T., Riccieri, P. & Furlani, C. (1969)J. Inorg. Nucl. Chem. 31, 3585.
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The authors are indebted to Prof. C. Furlani who kindly supplied the crystals of the compound.
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Chiesi, A., Mangia, A., Nardelli, M. et al. Crystal and molecular structure of tetrakis(N,N′-diallylthiourea)nickel(II) iodide. Journal of Crystal and Molecular Structure 1, 285–289 (1971). https://doi.org/10.1007/BF01200422
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DOI: https://doi.org/10.1007/BF01200422