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Synthesis and structural characterization of bismuth complexes with sulphur-containing ligands: The crystal and molecular structures of two derivatives of BiBr3 and Bi2(SO4)3 with imidazolidine-2-thione

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Abstract

The paper reports the structural and spectroscopic properties of two complexes between BiBr3, Bi2(SO4)3 and imidazolidine-2-thione (etu) having formulae BiBr3·3etu (I) and [Bi(etu)4]2(SO4)3·2H2O (II). ComplexI is monoclinic, space groupP21/n,Z=4, witha=8.142(2),b=15.611(3),c=16.316(3) Å,β=97.38(3)°,R=0.041.II is orthorhombic, space groupPbcn,a=10.930(1),b=16.795(1),c=27.890(1) Å,Z=4 andR=0.052. In both structures bismuth is octahedrally coordinated, inI three bromines and three sulphurs from etu molecules are present and the coordinated polyhedron is only moderately deformed, while inII four sulphurs of etu ligands and two oxygen sulphate with very different Bi-O distances [2.413(12) and 2.715(13) Å] are present.

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  1. Istiuto di Chimica Generale ed Inorganica, Centro di Studio per la Strutturistica Diffrattometrica del CNR, Viale delle Scienze, I-43100, Parma, Italy

    L. P. Battaglia, A. Bonamartini Corradi & G. Pelosi

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  1. L. P. Battaglia
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  2. A. Bonamartini Corradi
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  3. G. Pelosi
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Battaglia, L.P., Corradi, A.B. & Pelosi, G. Synthesis and structural characterization of bismuth complexes with sulphur-containing ligands: The crystal and molecular structures of two derivatives of BiBr3 and Bi2(SO4)3 with imidazolidine-2-thione. Journal of Crystallographic and Spectroscopic Research 22, 275–279 (1992). https://doi.org/10.1007/BF01199529

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  • DOI: https://doi.org/10.1007/BF01199529

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