Abstract
The title compounds have been synthesized, characterized by spectroscopic and analytical methods, and the complete structure of (IV) determined by single-crystal X-ray methods. Compound (IV) is monoclinic:a=13.891(3),b=4.935(2),c=12.499(2)Å,β=112.10(1) deg,P21/n,Z=4. The structure was determined by the heavy-atom method, and refined by full-matrix least squares onF toR=4.6%, with 1283 reflexions for whichI≥3σ (I). The structure (IV) was confirmed, and the molecule was shown to be planar to within 0.01 Å.
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References
Brown, R. N. (1961)Acta Crystallogr. 14, 711.
Cromer, D. T., and Liberman, D. (1970)J. Chem. Phys. 53, 1891.
Cromer, D. T., and Mann, I. B. (1968)Acta Crystallogr. A 24, 321.
Elvidge, J. A., and Linstead, R. P. (1954)J. Chem. Soc. 445.
Jabay, O., Pritzkow, H., and Jander, J. (1977)Z. Naturforsch. 32B, 1416.
Stewart, J. M. (1980) (Ed.)The X-Ray System-Version of 1980, Technical Report TR 446, Computer Center, University of Maryland.
Stewart, R. F., Davidson, E. R., and Simpson, W. T. (1975)J. Chem. Phys. 62, 3175.
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Greenwood, P.A., Ladd, M.F.C. & Povey, D.C. Synthesis, spectroscopy, and structures of 2-bromo-1-bromoimino-3-oxo-isoindoline(III) and 1-bromoimino-3-oxoisoindoline(IV). Journal of Crystallographic and Spectroscopic Research 22, 259–263 (1992). https://doi.org/10.1007/BF01199526
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DOI: https://doi.org/10.1007/BF01199526