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Catalytic hydrocondensation of carbon monoxide with olefins Communication 8. Hydrocondensation of carbon monoxide with 2-methylpropene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of catalytic hydrocondensation of carbon monoxide with straight-chain olefins has been extended to the simplest branched olefin, 2-methylpropene.

  2. 2.

    The average yield of liquid condensate was 550–650 ml/cu.m, or 62-69 ml/liter.hr, and the maximum yield attained 785 ml/cu.m, or 87 ml/liter.hr.

  3. 3.

    The liquid condensate contained 11% of unsaturated, hydrocarbons and, after complete hydrogenation, 86.6% distilled over below 157°.The contents of C5-, C6-, C7-, and and C8- fractions wErel2,22,22 and 12% respectively. These fractions consist essentially of hydrocarbons having a methyl side group on the second carbon of the chain, i.e. 2-methylbutane, 2-methylpentane, 2-methylhexane, and 2-methylheptane respectively.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    Ya. T. Eidus, K. V. Puzitsky & M. I. Batuev

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  1. Ya. T. Eidus
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  2. K. V. Puzitsky
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  3. M. I. Batuev
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Eidus, Y.T., Puzitsky, K.V. & Batuev, M.I. Catalytic hydrocondensation of carbon monoxide with olefins Communication 8. Hydrocondensation of carbon monoxide with 2-methylpropene. Russ Chem Bull 1, 859–861 (1952). https://doi.org/10.1007/BF01198878

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  • DOI: https://doi.org/10.1007/BF01198878

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