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Dechlorination of hexachloroethane by trialkyl phosphites

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It has been shown that, when trialkyl phosphites, react with hexachloroethane, the corresponding alkyl chlorides and dialkyl phosphorochloridates are formed together with tetrachloroethylene.

  2. 2.

    It has been established that trialkyl phosphites may be used as dechlorinating agents for highly chlorinated paraffins.

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Literature cited

  1. Gilm Kamai, Proc. Acad. Sci. USSR, 55, 228 (1947); J. Gen. Chem. 16, 1522 (1946); Proc. Acad. Sci. `USSR, 66, 388 (1949); 70, 233(1950); 79, 795 (1951).

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Authors and Affiliations

  1. S. M. Kirov Kazan Chemico Technical Institute, USSR

    G-ilm Kamai

  2. A. E. Arbuzov Chemical Institute of the Kazan Affiliated Institute of the,USSR Academy of Sciences, USSR

    G-ilm Kamai

Authors
  1. G-ilm Kamai
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Kamai, Gi. Dechlorination of hexachloroethane by trialkyl phosphites. Russ Chem Bull 1, 819–820 (1952). https://doi.org/10.1007/BF01198870

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  • DOI: https://doi.org/10.1007/BF01198870

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