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Preparation of cyclic acid chlorides and mixed esters derived from (alkoxymethyl)ethylene hydroden arsenites and trimethylene hydrogen arsenite

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of new cyclic acid chlorides derived from (alkoxymethyl)ethylene hydrogen arsenites and from trimethylene hydrogen arsenite.

  2. 2.

    It has been found that, in the preparation of (methoxymethyl)ethylene arsenochloridite and of trimethylene arsenochloridite in a medium of ether and pyridine, full cyclic esters are formed at the same time.

  3. 3.

    Mixed arsenious esters containing the bivalent radical (methoxymethyl)ethylene have been investigated.

  4. 4.

    It has been shown that the arsenochloridites and mixed esters that have been synthesized are hydrolyzed by water with formation of arsenious oxide and of the corresponding glycols and alcohols.

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Literature cited

  1. McKenzie and Wood. J. Chem. Soc., 117, 406 (1920).

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  2. Gilm Kamai, and Z.L.Khisamova. Proc. Acad. Sci. USSR, 76, 535 (1951).

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Authors and Affiliations

  1. A.E. Arbuzov Chemical Institute of the Kazan Affiliated Institute of the USSR Academy of Sciences, USSR

    Gilm Kamai & N. A. Chadaeva

Authors
  1. Gilm Kamai
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  2. N. A. Chadaeva
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Kamai, G., Chadaeva, N.A. Preparation of cyclic acid chlorides and mixed esters derived from (alkoxymethyl)ethylene hydroden arsenites and trimethylene hydrogen arsenite. Russ Chem Bull 1, 807–811 (1952). https://doi.org/10.1007/BF01198868

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  • DOI: https://doi.org/10.1007/BF01198868

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